The rising level of atmospheric carbon dioxide (CO₂) is a major driver of climate change, highlighting the need to develop carbon capture and storage (CCS) technologies quickly. This paper offers a comparative review of three main groups of porous adsorbent materials—zeolites, metal–organic frameworks (MOFs), and activated carbons—for their roles in CO₂ capture and long-term storage. By examining their structural features, adsorption capacities, moisture stability, and economic viability, the strengths and weaknesses of each material are assessed. Additionally, five different methods for delivering these materials into depleted oil and gas reservoirs are discussed: direct suspension injection, polymer-assisted transport, foam-assisted delivery, encapsulation with controlled release, and preformed particle gels. The potential of hybrid systems, such as MOF–carbon composites and polymer-functionalized materials, is also examined for improved selectivity and durability in underground environments. This research aims to connect materials science with subsurface engineering, helping guide the selection and use of adsorbent materials in real-world CCS applications. The findings support the optimization of CCS deployment and contribute to broader climate change efforts and the goal of achieving net-zero emissions. Key findings include CO₂ adsorption capacities of 3.5–8.0 mmol/g and surface areas up to 7000 m²/g, with MOFs demonstrating the highest uptake and activated carbons offering cost-effective performance.

Methyl esters derived from vegetable oils by the process of transesterification (commonly referred as ‘biodiesel’), can be used as an alternative fuel in compression ignition engines. In this study, three different vegetable oils (rape, soy and waste oil) were used to produce biodiesel fuels that were then tested in a four cylinder direct injection engine, typically used in small diesel genset applications. Engine performance and emissions were recorded at five load conditions and at two different speeds. This paper presents the results obtained for measurements of NOx and smoke opacity at the different speed and load conditions for the three biodiesels, and their blends (5 and 50% v/v) with mineral diesel. A simple combustion analysis was also performed where ignition delay, position and magnitude of peak cylinder pressure and heat release rate were examined to asses how the variation of chemical structure and blend percentage affects engine performance. Engine performance and emissions for all of the 5% biodiesel blends were indistinguishable from mineral diesel. However, at higher blends, the rape fuel exhibited better emission and performance characteristics than either the soy or waste fuels. Furthermore; whilst emissions trends varied for each blend and fuel, emissions of smoke were significantly reduced at all speed and load conditions, and NOx was reduced by up to 50% at low loads. It will also be shown that while engine performance was not significantly deteriorated by biodiesel, there was evidence of increased ignition delay with higher blends, and a possible two stage ignition process where mineral diesel ignited earlier than the biodiesel.

Unconventional reservoirs, including gas shales and tight gas sands, have gained prominence in the energy sector due to technological advancements and escalating energy demands. The oil industry is eagerly refining techniques to decipher these reservoirs, aiming to reduce data collection costs and uncertainties in reserve estimations. Characteristically, tight reservoirs exhibit low matrix porosity and ultra-low permeability, necessitating artificial stimulation for enhanced production. The efficacy of the stimulation hinges on the organic material distribution, the rock’s mechanical attributes, and the prevailing stress field. Comprehensive petrophysical analysis, integrating standard and specialized logs, core analyses, and dynamic data, is pivotal for a nuanced understanding of these reservoirs. This ensures a reduction in prediction uncertainties, with parameters like shale volume, porosity, and permeability being vital. This article delves into an intricate petrophysical evaluation of the Nene field, a West African unconventional reservoir. It underscores the geological intricacies of the field, the pivotal role of data acquisition, and introduces avant-garde methodologies for depth matching, rock typing, and the estimation of permeability. This research highlights the significance of unconventional reservoir exploration in today’s energy milieu, offering a granular understanding of the Nene field’s geological challenges and proffering a blueprint for analogous future endeavours in unconventional reservoirs.