The impurities present in carbon dioxide (CO2) streams for Carbon Capture and Storage (CCS) schemes are extremely important for CO2 pipeline and ship transportation affecting, for instance, the range of operation, safety considerations, fracture, cracking, corrosion control, dispersion in the event of a release, fluid density, operating pressure and temperature and the quantity of CO2 that can be transported. The range and levels of potential impurities present in captured CO2 from CO2 capture facilities will differ between sources and also between the capture technologies installed at the CO2 emission sources. However, the potential CO2 specifications that could enter the transport and storage systems, particularly from industrial sources, remain relatively under-researched. Consequently, the effect of these potential impurities in CO2 streams on CO2 transportation also needs to be understood. This paper summarises the main findings of an IEAGHG study, “Impact of CO2 Impurity on CO2 Compression, Liquefaction and Transportation”, commissioned to identify potential impurities and address the consequences of their impact on CO2 transportation

Supported polyethyleneimine (PEI) adsorbent is one of the most promising commercial direct air capture (DAC) adsorbents with a long research history since 2002. Although great efforts have been input, there are still limited improvements for this material in its CO₂ capacity and adsorption kinetics under ultradilute conditions. Supported PEI also suffers significantly reduced adsorption capacities when working at sub‐ambient temperatures. This study reports that mixing diethanolamine (DEA) into supported PEI can increase 46% and 176% of pseudoequilibrium CO₂ capacities at DAC conditions compared to the supported PEI and DEA, respectively. The mixed DEA/PEI functionalized adsorbents maintain the adsorption capacity at sub‐ambient temperatures of −5 to 25 °C. In comparison, a 55% reduction of CO₂ capacity is observed for supported PEI when the operating temperature decreases from 25 to −5 °C. In addition, the supported mixed DEA/PEI with a ratio of 1:1 also shows fast desorption kinetics at temperatures as low as 70 °C, resulting in maintaining high thermal and chemical stability over 50 DAC cycles with a high average CO₂ working capacity of 1.29 mmol g⁻¹. These findings suggest that the concept of “mixed amine”, widely studied in the solvent system, is also practical to supported amine for DAC applications.