ZLB GF separator was prepared based on a conventional GF separator through a simple self-assembly method that can realize dendrite free aqueous zinc ion batteries.

This study investigates the influence of micro-arc oxidation (MAO) duration on the formation and characteristics of ceramic coatings on 6061 aluminum alloys. MAO treatments were conducted in a silicate-based electrolyte for varying durations. The effects of oxidation time on film thickness, surface roughness, morphology, and phase composition were meticulously assessed using a film thickness gauge, surface roughness meter, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analysis. The corrosion behavior of the coatings was evaluated in a 3.5% NaCl solution using an electrochemical workstation. The experimental results demonstrate that both the film thickness and surface roughness exhibit a positive correlation with oxidation time. Notably, the film growth rate initially increased before plateauing, suggesting an optimal oxidation duration. The coatings primarily comprise γ-Al₂O₃, α-Al₂O₃, and Al phases, with the proportions of γ-Al₂O₃ and α-Al₂O₃ increasing progressively with extended oxidation times. Comparative electrochemical tests revealed that the treated specimens exhibited significantly higher corrosion potential and reduced corrosion current densities compared to the untreated aluminum alloy substrate. Specifically, a coating produced with a 20 min oxidation time demonstrated an exceptional corrosion current density (J_corr) of 1.545 × 10⁻⁶ A·cm⁻² and a corrosion resistance (R_p) of 2.716 × 10⁴ Ω·cm², signifying the best corrosion resistance achieved in this study. These results underscore the pivotal role of oxidation time in tailoring the properties of micro-arc-oxidized layers on 6061 aluminum alloys, offering valuable insights for enhancing corrosion protection in practical applications.

Aqueous zinc ion batteries (AZIBs) have emerged as a promising battery technology due to their excellent safety, high capacity, low cost, and eco-friendliness. However, the cycle life of AZIBs is limited by severe side reactions and zinc dendrite growth on the zinc electrode surface, hindering large-scale application. Here, an electrolyte optimization strategy utilizing the simplest dipeptide glycylglycine (Gly-Gly) additive is first proposed. Theoretical calculations and spectral analysis revealed that, due to the strong interaction between the amino group and Zn atoms, Gly-Gly preferentially adsorbs on zinc’s surface, constructing a stable and adaptive interfacial layer that inhibits zinc side reactions and dendrite growth. Furthermore, Gly-Gly can regulate zinc ion solvation, leading to a deposition mode shift from dendritic to lamellar and limiting two-dimensional dendrite diffusion. The symmetric cell with the addition of a 20 g/L Gly-Gly additive exhibits a cycle life of up to 1100 h. Under a high current density of 10 mA cm⁻², a cycle life of 750 cycles further demonstrates the reliable adaptability of the interfacial layer. This work highlights the potential of Gly-Gly as a promising solution for improving the performance of AZIBs.

The huge volume expansion of over 300%, dreadful electrical conductivity and labile solid electrolyte interphase (SEI) are the principal reasons of the sluggish development of Si anodes for lithium-ion batteries (LIBs). Therefore, we propose, for the first time, that titanium nitride (TiN) be utilized as a coating layer to fabricate yolk–shell-structured Si@TiN nanoparticles. The design of the yolk–shell structure can reserve excrescent space for the volume expansion of Si electrodes, which helps to mitigate volumetric changes. Moreover, the TiN protecting layer is beneficial to the formation of a stable and flimsy SEI film, avoiding the excessive consumption of electrolytes. Finally, the ultrahigh conductivity (4 × 10⁴ S cm⁻¹) as well as the high mechanical modulus of TiN can significantly promote charge transfer and avoid the crushing of the SEI film caused by excessive local stress during reduplicative Li deposition/stripping. Accordingly, the Si@TiN composites show excellent electrochemical properties and suppressed volume expansion compared with pure silicon nanoparticles (Si NPs). Here, these yolk–shell-structured Si@TiN nanoparticles exhibit improved rate performance and excellent long cycling stability with 2047 mA h g⁻¹ at 1000 mA g⁻¹ after 180 cycles. This paradigm may provide a feasible engineering protocol to push the properties of Si anodes for next-generation LIBs.

The CBS additive synergistically inhibits dendrite growth by reconstructing the Zn ²⁺ solvation sheath and inducing a ZnS interfacial layer, significantly enhancing the cycling stability of zinc anodes.