The soils above caves represent a membrane that regulates the connection between the underground environment and the outside atmosphere. In this study, soils from two different field sites (Cueva de Altamira and Cueva del Rull in Spain) are investigated. Field results are analysed and linked to laboratory tests. Several laboratory experiments are performed to quantify CO2 diffusion coefficients and water infiltration rates in these soils under different degrees of soil water saturation and compaction. Tests confirm that the grain size distribution, organic matter content, mineral composition and water content of soils affect gas transport through the soil pore network. Both field and lab results reveal that Altamira soil has a coarser texture and therefore has higher CO2 diffusion coefficients, infiltration rates and hydraulic conductivity values than Rull soil. Rull soil contains a higher proportion of fine particles and organic matter, which explains the lower fluid transport coefficients. When soils are near saturation, fluid transport does not depend on the physical properties of soil but depends on the soil water content. In this state, liquid transport regulates the available space within the soil pores, which leads to a reduction in the gaseous diffusion coefficient of the soil. After rainfall episodes, the connection between the exterior atmosphere and underground cavities is hindered due to a rise in the soil water content, which is responsible for the closure of the overlying membrane. This study demonstrates that soil-produced CO2 reaches the underground atmosphere through diffusion processes that are controlled by the intrinsic properties of soil (porosity, grain size distribution, texture, mineralogy and organic matter content) and soil water content.This research was funded by the Spanish Ministry of Economy and Competitiveness projects CGL2011-25162 and CGL2013-43324-R and its programme Torres Quevedo (PTQ 13-06296). A pre-doctoral research fellowship (BES-2012-053468) was awarded to C. Pla for the project CGL2011-25162. Funding was also provided by the People Programme (Marie Curie Actions–Intra-European Fellowships, call 2013) of the European Union's Seventh Framework Programme (FP7/2007–2013) under the REA grant agreement n° 624204

A mineralogical and microtextural study of Somosaguas Miocene deposits, located in the Madrid Basin (western Madrid, Spain), was carried out using X-ray diffraction, scanning electron microscopy, transmission electron microscopy and optical microscopy, whereas crystal chemistry data were obtained by analytical electron microscopy-transmission electron microscopy and electron icroprobe analysis. Four stratigraphic sections were studied, compising detrital rocks representing intermediate and distal facies from alluvial fan deposits. The predominant source area of these sediments was the granitic rocks of the Spanish Central System with a lesser contribution of metamorphic rocks. Clayey arkoses are the most abundant rocks of these sections, typical of granite alteration under warm, semi-arid climates. The mineralogy is characterized by phyllosilicates, followed by feldspars and quartz. The data obtained reveal mineral mixtures of detrital (quartz, feldspars, kaolinite, micas and chlorite), transformed (illite and beidellite) and neoformed (montmorillonite) origin. Clay minerals resulted from interactions between detrital minerals and meteoric waters. Two trends of degradation of micas are detected. The first shows a transition from muscovites and dioctahedral illites, to beidellites. The other trend is defined by the biotite degradation to beidellites with different layer charge and octahedral Fe content. Montmorillonites were neoformed from the hydrolysis and weathering of primary minerals (feldspars and muscovite). Magnesian clay minerals such as sepiolite, palygorskite and trioctahedral smectites, extremely abundant in the centre of the basin, were not detected in Somosaguas sediments.

We present a methodological approach for the representation, visualisation and analysis of three-dimensional (3D) models of meaningful details in stone reliefs provided by digital documentation tools and subsequent processing. For this aim, anthropomorphous shapes engraved on a flat stone slab found in Sierra de Fontcalent (Alicante) are studied. The object under consideration was located near two archaeological sites, Cova del Fum -a cave with presence of the Chalcolithic material (Lopez, 2010)- and the archaeological site of Fontcalent, with remains from different phases of occupation spanning from 7th-6th BC to the 20th century (Ximenez, 2012). In the last few years, the use of digital tools provided by new technologies and software development has left traditional work methodology behind (De Reu et al., 2014) while enabling the development of new approaches to both minimise heritage alteration and provide objective and accurate information (Lopez-Menchero, Marchante, Vincent, Cardenas, & Onrubia, 2017). 3D documentation allows recording of cultural heritage at a reasonable cost with precision and quality through digital photography and SfM (Structure from Motion) photogrammetry with specialised software (De Reu et al., 2013). In this project, recording and documentation with digital photography and automated photogrammetric techniques are applied to the Fontcalent stone slab for its digitisation and subsequent 3D representation. From the resulting model, a two-folded line of study is obtained. On the one hand, a Digital Elevation Model (DEM) is generated to study the microtopographies of the stone with geographic analysis techniques provided by Geographic Information Systems (GIS) from different lighting conditions and surface reflections, which are calculated by hillshading or LRM (Local Relief Model) for the interpretation of the object (Carrero-Pazos, Vilas, Romani, & Rodriguez, 2014; Gawior, Rutkiewicz, Malik & Wistuba, 2017). On the other hand, from both the 3D model and the point cloud, the study is completed with the application of the methods of analysis and visualisation based on the Morphological Residue Model (MRM) which stands out every single detail of the surface morphology of the object (Caninas, Pires, Henriques, & Chambino, 2016; Correia, Pires, & Sousa, 2014). Further visualisations are based on Reflectance Transformation Imaging (RTI) which provides different shadows and reflections over the object from the application of a multidirectional illumination (Happa et al., 2010; Malzbender, Gelb, Wolters, & Zuckerman, 2000; Mudge et al., 2010). The results thus obtained of the Fontcalent stone slab allow us to visualise several characteristic elements. The anthropomorphous figure awaking interest is also combined with the figure resulting from different visualisations applied with GIS techniques which may resemble a zoomorph. The use of visualisation techniques shown in this study has been fundamental in order to recognise the latter element. The composition reveals a zigzag line already appreciated before the study so that it is interesting to check if visualisations based on GIS techniques are able to highlight it though being shallow incisions. In our experience regarding this study, visualisation by using the hillshading technique shows a greater level of 3D detail than that provided by the application of the sky-view factor technique which offers a flattering view. However, the former technique may occasionally show shadows which hide other details, unlike the latter technique which plots the entire slab surface illuminated while differentiating the associated microtopography on the basis of its marks. The use of shaders in combination with hillshading and particularly combined with high pass filtering, contributes to improving the visualisation and accuracy of shadowed areas. As a result, we conclude that the results obtained in this work by lighting techniques with GIS add a greater level of detail in comparison to those provided by the mesh or the point cloud. The study of the Fontcalent stone slab paves the way for two working hypotheses to be developed: on the one hand, its anthropological origin possibly related to the Chalcolithic, and on the other hand, its study as natural geological formations with ichnofossils. The digitisation of cultural heritage with available 3D technologies should be a mandatory requirement when facing any study, analysis or intervention. With the current development of such techniques, we have verified their contribution to fundamental characteristics in the corresponding stages of visualisation and study. Thus, the proposed methodology is presented as an accurate and complete alternative for the study and analysis of the existing cultural heritage, and opens new ways for the revision, reinterpretation and revaluation of the previously evaluated heritage through traditional techniques.