Conjugated polymers have gained considerable interest due to their unique structures and promising applications in areas such as optoelectronics, photovoltaics, and flexible electronics. This review focuses on the structure–property relationship, glass transition, and crystallization behaviors of conjugated polymers. Understanding the relationship between the molecular structure of conjugated polymers and their properties is essential for optimizing their performance. The glass transition temperature (T_g) plays a key role in determining the processability and application of conjugated polymers. We discuss the mechanisms underlying the glass transition phenomenon and explore how side-chain interaction affects T_g. The crystallization behavior of conjugated polymers significantly impacts their mechanical and electrical properties. We investigate the nucleation and growth processes, as well as the factors that influence the crystallization process. The development of the three generations of conjugated polymers in controlling the crystalline structure and enhancing polymer ordering is also discussed. This review highlights advanced characterization techniques such as X-ray diffraction, atomic force microscopy, and thermal analysis, which provide insights into molecular ordering and polymer–crystal interfaces. This review provides an insight of the structure–property relationship, glass transition, and crystallization behaviors of conjugated polymers. It serves as a foundation for further research and development of conjugated polymer-based materials with enhanced properties and performance.

Binary PtBi decorated nanoporous gold (NPG-PtBi) electrocatalyst is specially designed and prepared for the anode in direct glucose fuel cells (DGFCs). By using electroless and electrochemical plating methods, a dense Pt layer and scattered Bi particles are sequentially coated on NPG. A simple DGFC with NPG-PtBi as anode and commercial Pt/C as cathode is constructed and operated to study the effect of operating temperatures and concentrations of glucose and NaOH. With an anode noble metal loading of only 0.45 mg cm⁻² (Au 0.3 mg and Pt 0.15 mg), an open circuit voltage (OCV) of 0.9 V is obtained with a maximum power density of 8 mW cm⁻². Furthermore, the maximum gravimetric power density of NPG-PtBi is 18 mW mg⁻¹, about 4.5 times higher than that of commercial Pt/C.

Environmental pollution has been widely considered by researchers, especially the heavy metals damage to the human and ecological environment is irreversible. Adsorption is an important method to remove heavy metal ions from the environment. In this paper, humic acid (HA) was functionalized by the improved Hummers method, and its adsorption capacity for Pb(II) was studied. The results of scanning electron microscope (SEM), X-ray diffraction (XRD), Roman, and Brunauer-Emmett-Teller (BET) showed that the thickness of irregular particles decreases to a layered structure during the transformation process. In addition, X-ray photoelectron spectroscopic (XPS) and Fourier transform infrared spectra (FT-IR) spectra showed that the surface of oxidized-biochar (OBC) was rich in reactive oxygen species, which was conducive to the formation of coordination bonds with Pb(II). Further adsorption experiments showed that it was a spontaneous monolayer chemisorption. The results of the DFT calculation showed that -COOH had the lowest adsorption energy for Pb(II), and it was easier to form stable chemical bonds than -OH, -C=O, and -C-O-C-. Because those oxygen-containing functional groups not only can promote electrostatic attraction but also are more favorable for forming a covalent bond with Pb(II). This study had guiding significance for the deep modification and application of weathered coal as a heavy metal ion adsorbent or cation exchanger.