This work aims to evaluate the thermal degradation of carboxymethyl cellulose (CMC) in solution in the presence of salt, as well as to study the correlation of the rheological behavior of these solutions with exposure to temperature. Step 1 involved characterizing powdered low- and high-viscosity CMC using SEM, FTIR, TGA/DrTGA, and DSC. In step 2, CMC solutions in fresh and saline water were characterized by TGA/DrTGA and viscosity tests. Step 3 exposed saline solutions to 70–150 °C for varying times, followed by TGA/DrTGA and viscosity analyses. There were no significant differences in the thermal degradation of LV and HV CMC, nor in terms of the physical state of the polymer. The results demonstrate that the use of CMC necessitates a combined analysis of thermal degradation and rheological behavior.

Palygorskite has shown satisfactory performance in salted water-based fluids, especially as a rheological agent. However, this type of formulation has been used in the petroleum industry only in well drilling operations. This study proposes the development of a salted water-based fluid with palygorskite, which presents an adequate performance as a liquid barrier element in temporary abandonment operations of wells. Based on a factorial design, seven fluid formulations were prepared with varying concentrations of palygorskite and PAC LV and were tested by measuring the HPHT filtrate volume, rheological properties, density, and pH. For comparison purposes, the results of the seven formulations were evaluated against a formulation without palygorskite and analyzed for their performance in abandonment operations. The results showed that the presence of palygorskite reduces filtrate volumes by at least 21%, thereby helping control the pressure exerted by the fluid column, which is the primary requirement for abandonment operations. Furthermore, the fluid that contained the highest amount of palygorskite and PAC LV (20 g and 8 g, respectively) showed the best results regarding filtrate control (11.2 mL) and solid sedimentation. Therefore, it is a very promising alternative for use as a well barrier element in the temporary abandonment of wells.

This study aims to evaluate how the operational procedure adopted for pellet placement and the exposure to subsurface conditions influence the mechanical integrity of bentonite plugs used as barrier elements in the abandonment of petroleum wells. To this end, the plugs were formed by hydrating the pellets directly in water, simulating the onshore procedure, while the offshore plugs were obtained from pellets hydrated in deionized water after immersion in diesel or olefin, which are suggested as displacement fluids. The plugs obtained were tested by compression and adhesion tests. These mechanical tests were also carried out for specimens obtained from plugs exposed to four formulations of synthetic formation waters. The results obtained demonstrated that, in the offshore procedure, the previous contact with olefin may adversely affects the mechanical stability of bentonite plugs, while plugs formed from pellets immersed in diesel presented satisfactory mechanical properties. However, the contact with formation water evidenced that the onshore plug presents superior resistance than the offshore plug previously immersed in diesel. The highly successful performance of the onshore plug was attested by the maintenance of the compressive strength, which exhibited a maximum reduction of 13%, even after exposure to the most saline formation waters.

This work aimed to correlate the reactivity and mineralogical composition of shales to their disintegration. To accomplish this, five samples of shale from Rio do Peixe Basin and Araripe Basin, located in the Brazilian States of Paraíba and Ceará, respectively, were characterized. A sample of industrialized bentonite clay was used as a reference to provide a comparison. Characterization was performed through cation exchange capacity, particle size analysis, X-ray fluorescence, and X-ray diffraction. Disintegration tests were performed according to the American Petroleum Institute standards in the presence of deionized water, aqueous potassium citrate solution, and drilling fluid. The results suggested that samples presenting no reactive clay mineral content may be unstable and the higher the reactivity of the samples to aqueous fluids does not necessarily imply a higher level of disintegration. This demonstrated that different mechanisms not associated with clay swelling may assume greater or lesser relevance on the instability of a formation.

The chemical nature of solids incorporated into the drilling fluid can be very diverse, since it is related to the type of rock formation. As a result, it can lead to different impacts on the properties of the emulsions, which are the bases for drilling fluids formulation. In view of this, this work aimed to evaluate the influence of the chemical nature of finely divided solids on physical properties and interfacial phenomena of inverse olefin emulsions. For this purpose, emulsions were prepared using linear olefin and NaCl brine, as continuous and dispersed phases, respectively. Each emulsion was incorporated with limestone and clay, in the proportion of 5% v/v. The emulsions were characterized by means of optical microscopy, rheological behavior and gravitational separation tests. The results showed that chemical nature and particle size of bentonite clay ensures a more efficient interfacial interaction with emulsion droplets. The emulsion added with bentonite clay showed a significant increase in consistency index and smaller separated volume. Thus, the addition of bentonite clay to olefin emulsions resulted in changes on its properties, which contributes to emulsion stability. Graphical Abstract

Glycerin-based fluids are proposed as a promising alternative to inhibited fluids in the drilling of highly-reactive formations. However, even with the use of these fluids, it is still possible to observe the occurrence of problems related to the balling of drill bits and drill pipes, such as the agglomeration and accretion of cuttings. This study aims to analyze how the interaction between expandable minerals from reactive formations and glycerin-based drilling fluids affects the stability of oil wells, focusing on the occurrence and extent of the accretion phenomenon. For this purpose, bentonite pellets were characterized regarding their mineralogical composition and plastic behavior. In addition, accretion tests were performed in order to evaluate the interaction between bentonite pellets and glycerin-based drilling fluids containing different types of inhibitors. The results revealed that the pellets were predominantly composed of interstratified illite–smectite (IS) clay minerals and presented highly plastic properties with a high degree of expansion. Furthermore, it was found that the accretion percentages were significant for all the fluids studied, at higher than 58%. Therefore, it was found that using glycerin in drilling fluids did not stabilize expandable minerals in reactive formations, even with different expansion inhibitors, which were ineffective in reducing the rock expansibility.