Graphene-based materials have great potential for tribological applications. Graphene’s unique properties such as low shear resistance, high stiffness, and thermal conductivity make it an attractive material for improving the properties of lubricants in a wide range of industrial applications, from vehicles to house refrigerators and industrial machinery such as gearboxes, large compressors, etc. The current review aims to give an engineering perspective, attributing more importance to commercially available graphene and fully formulated lubricants instead of laboratory-scaled produced graphene and base oils without additives. The use of lubricants with graphene-based additives has produced e.g., an increase in mechanical efficiency, consequently reducing energy consumption and CO₂ emissions by up to 20% for domestic refrigerators and up to 6% for ICE vehicles. Potential effects, other than purely friction reduction, contributing to such benefits are also briefly covered and discussed.

Lubricant friction modifier additives are used on lower viscosity engine oils to mitigate boundary friction. This work presents the development of a graphene-based material as an oil friction modifier additive, from formulation to actual vehicle tests. The graphene material was initially characterized using scanning electron microscopy (SEM) and Raman spectroscopy, which revealed the predominance of graphene nanoplatelets (GNPs) with an average of nine layers. After functionalization, two GNP additive variants were initially mixed with a fully formulated SAE 0W-20 engine oil and tribologically evaluated using reciprocating sliding tests at 40 and 120 °C and Hertzian pressure up to 1.2 GPa when both variants presented friction reduction. Then, the GNP additive variant with better performance was evaluated in a vehicle emission test using a fully formulated 5W-20 SAE oil as a reference. The addition of 0.1% of GNPs reduced fuel consumption by 2.6% in urban conditions and 0.8% in highway ones. The urban test cycle was FTP75 and higher benefits of the GNP additive occurred especially on the test start, when the engine and oil were still cold and on test portions where the vehicle speed was lower.

The growing awareness of reduced friction losses and new demands for electrical powertrains demand improved lubricants. Due to their unique properties, such as high thermal and electrical conductivity, graphene and its derivatives have been investigated for tribological applications, especially as lubricant additives. In this work, we investigated three commercially available graphene variants, one comprising a few layers and the other two comprising nanoplates, after functionalization as additives to lithium soap grease. The grease temperature dropping point increased by approximately 6 °C. Additionally, during the reciprocating friction test, friction increased with the test duration for the baseline grease, whereas it decreased for the ones containing graphene-based additives. On the test end, friction was reduced by 8% compared to the baseline grease. On a four-ball tribometer, the wear scar was reduced from 10 to 18% compared to the baseline grease. In general, no significant difference was seen between the three graphene-based variants. The promising results found with graphene nanoplates, a less expensive material than a few graphene layers, creates opportunities for a cost-competitive additive to commercial greases.