The tanning industry generates effluents with high chromium content, which require treatment prior to discharge into the sewage system. This article explores the use of magnetic magnetite nanoparticles (MNPs) to remove Cr(VI) from aqueous solutions, such as tanning effluents. The MNPs were synthesized by coprecipitation reaction using the Olea europaea extract as a reducing agent. Subsequently, they were characterized by dynamic light scattering spectroscopy (DLS), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). MNPs with irregular morphology and diameters ranging from 73.28 to 162.90 nm were obtained. Cr(VI) removal was performed using jar test methodology, and its efficiency was evaluated in the laboratory for different initial Cr(VI) (mg/L) concentration and nanoparticle (g/L) concentration. A kinetic study was developed and indicated that the equilibrium adsorption mechanism corresponds to a pseudo-second-order model. Furthermore, the isotherm analysis revealed that chromium adsorption best fits the Langmuir isotherm. Finally, Cr(VI) removal rates from 85% to 100% were achieved in tanning and retanning effluents.
28 December 2024 in Case Studies in Chemical and Environmental Engineering
Arequipa, situated in the arid Atacama Desert, is experiencing significant biodiversity loss due to unchecked urban growth. This study presents the design of a Botanical Garden to address this issue by serving as a conservation center for native flora. A baseline assessment was conducted to evaluate meteorological conditions, soil properties, and the quality of treated wastewater from the “La Escalerilla” plant. The analysis revealed a semi-arid climate with low precipitation and suitable soil conditions. A total of 685 plant species were identified and proposed for conservation within the garden, with a high proportion of endemic species. To protect the future plant species, a living fence composed of 700 individuals was installed, considering resilient species such as Molle serrano (Schinus molle), Cantuta (Cantua buxifolia), and Huaranguillo (Tephrosia cinerea), which were installed at an average height of 50 cm and have grown to an average of 80 cm after 8 months. This study demonstrates the feasibility of establishing a botanical garden in Arequipa’s arid environment and serves as a model for future botanical garden projects in arid regions at the national and regional levels, providing a foundation for natural landscapes in urban areas.