The current study focuses on the production of biochars derived from aquatic plants, specifically red seaweed Ahnfeltia and seagrass Zostera and Ruppia, found in brackish lagoons in the Sea of Okhotsk, Sakhalin Island. These biochars were obtained through a stepwise pyrolysis process conducted at temperatures of 500 and 700 °C. The characteristics of the biochars, including their elemental composition, specific surface area, and particle size distribution, were found to be influenced by both the type of biomass used and the pyrolysis temperature. The primary objective of this research was to investigate the potential of these biochars to be used as negative electrodes for lithium ion batteries. Among the various samples we tested, the biochar derived from the macroalgae Ahnfeltia tobuchiensis, produced at 700 °C, exhibited the highest carbon content (70 at%) and nitrogen content (>5 at%). The reversible capacity of this particular biochar was measured to be 391 mAh g⁻¹ during the initial cycles and remained relatively stable at around 300 mAh g⁻¹ after 25 cycles. These findings suggest that biochars derived from aquatic plants have the potential to be utilized as effective electrode materials in lithium ion batteries. The specific properties of the biochar, such as its elemental composition and surface area, play a significant role in determining its electrochemical performance. Further research and optimization of the pyrolysis conditions may lead to the development of biochar-based electrodes with improved capacity and cycling stability, thereby contributing to the advancement of sustainable and environmentally friendly energy storage systems.

Following a tendency of many economies to shift towards carbon neutrality, there came the necessity for certain regions to be assessed in terms of their greenhouse gas emissions from the ocean. A carbon polygon was created in Sakhalin Oblast in order to evaluate the carbon balance of this marine ecosystem in a sub-arctic region, with the possibility of deploying carbon farms for additional CO₂ absorption. To obtain such an assessment, it seems crucial to analyze hydrochemical parameters that reflect the situation of the marine environment in Aniva Bay as a basis of the carbon polygon. The article presents the results of the analysis of hydrochemical parameters in Aniva Bay waters and their spatial and seasonal variability. This research was based on available published sources and measurement databases for the period of 1948–1994. Additionally, the review uses hydrochemical data for Aniva Bay in 2001–2013 weather station data for the period of 2008–2023 and weather station data for 2008–2023. Some tendencies were discovered for spatial and temporal distributions of oxygen, pH, and biogenic matter (inorganic phosphorus, inorganic nitrogen, silicon). In surface layers, the mean oxygen year maximum (9.1 mg/L) is registered with the beginning of photosynthesis, i.e., immediately after the ice melting in April. The highest pH values 8.26 are registered in the euphotic layer in May. The lowest pH values was in August (7.96) in the near-bottom layer. The maximum annual P-PO4 registered on the surface (>18 µg/L) immediately after ice melting, with a minimum (7.17 µg/L) at the end of July. Si-SiO₃ concentrations have two maximums: at the end of June and at the beginning of October. N-NO2 concentration on the surface is >2 µg/L in mid-July and on the 50 m depth it is >3.5 µg/L in mid-September. Some spatial patterns of hydrochemical parameters were shown based on the analysis of maps.

In the present paper, the case of the brown algae Saccharina japonica from Aniva Bay (Sea of Okhotsk, Sakhalin Island) was investigated by a thermogravimetric analysis up to 700°C at different atmospheres. The elemental composition, lower heating value, ash content, and biochar yield of the algae were examined. The analysis showed that carbohydrates like alginate, mannitol, fucoidan, and laminarin were decomposed between 250-350°C, while proteins and lipids were burned out between 500-550°C.

The spatial distribution of eggs and larvae of the walleye pollock Theragra chalcogramma is considered in respect to dynamics of oceanologic processes, nutrients, chlorophyll а and zooplankton off the

To determine the risks for mariculture farms, the intra-annual change of dissolved О2 concentration was simulated for five zones in the Aniva Bay using the CNPSi model. Zone 1 differed sharply from other zones as the most shallow and freshened. Zone 2 is characterized by a pronounced water exchange with Zone 3 and Zone 4: during spring two layers were formed and stood out in these zones, in the summer the water column was homogeneous. Zone 3 has free water exchange with the open waters of the La Perouse Strait. An outstanding feature of Zone 4, in the deep-water part of the bay, was a distinctive subsidence of waters in the centre of the anticyclonic circulation and the maximum thermocline depth (up to 60-70 m). Zone 5 extends along the western coast of the Tonino-Aniva Peninsula and is characterized by the constant upwelling of waters during the icefree period, which is clearly expressed by lower water temperatures. The calculation showed that in the areas suitable for mariculture farms coastal waters were provided with oxygen throughout the year. Anaerobic conditions developed in spring only in the deepest parts of the bay. An additional source of oxygen in the Aniva Bay is natural thickets of macrophytes, among which the Japanese saccharin (Saccharina japonica) dominates in terms of biomass and area. Annually, Japanese saccharin itself absorbed at least 1200 tons of C in its biomass and supplied at least 3100 tons of О2. Unlike the artificially grown biomass, the biomass of all macrophytes would remain in the system and be destroyed during the life cycle, and the oxygen would be consumed for oxidation. The carbon accumulated in the biomass would again return to the rapid cycle, with the exception of the amount transported to the deep central part of the bay, where it would slowly decompose under nearly anaerobic conditions. It would be possible to place additional algae plantations in the bay, which could absorb up to 49 500 tons of C annually, while supplying up to 132 000 tons of О2. The obtained model estimates could be a starting point for determining the “baseline” of the content of dissolved oxygen and compiling balance equations for gas flows in the ocean-atmosphere system in the Aniva Bay before the development of seaweed plantations, which simultaneously act as carbon farms.