This study investigates three carbide-derived carbon (CDC) materials (TiC, NbC, and Mo₂C) characterized by uni-, bi-, and tri-modal pore sizes, respectively, for energy storage in both neat and acetonitrile-diluted 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. A distribution of micro- and mesopores was studied through low-temperature N₂ and CO₂ adsorption. To elucidate the relationships between porosity and the electrochemical properties of carbon materials, cyclic voltammetry, galvanostatic cycling, and electrochemical impedance spectroscopy measurements were conducted using three-electrode test cells. The ultramicroporous TiC-derived carbon is characterized by a high packing density of 0.85 g cm⁻³, resulting in superior cathodic and anodic capacitances for both neat ionic liquid (IL) and a 1.9 M IL/acetonitrile electrolyte (93.6 and 75.8 F cm⁻³, respectively, in the dilute IL). However, the bi-modal pore-sized microporous NbC-derived carbon, with slightly lower cathodic and anodic capacitances (i.e., 85.0 and 73.7 F cm⁻³ in the dilute IL, respectively), has a lower pore resistance, making it more suitable for real-world applications. A symmetric two-electrode capacitor incorporating microporous CDC-NbC electrodes revealed an acceptable cycle life. After 10,000 cycles, the cell retained approximately 75% of its original capacitance, while the equivalent series resistance (ESR) only increased by 13%.