This study aims to numerically assess the impact of wettability and relative permeability hysteresis on hydrogen losses during underground hydrogen storage (UHS) and explore strategies to minimize them by using an appropriate cushion gas. The research utilizes the Carlson model to calculate the saturation of trapped gas and the Killough model to account for water hysteresis. By incorporating the Land coefficient based on laboratory-measured data for a hydrogen/brine system, our findings demonstrate a significant influence of gas hysteresis on the hydrogen recovery factor when H₂ is used as a cushion gas. The base model, which neglects the hysteresis effect, indicates a recovery factor of 78% by the fourth cycle, which can be improved. In contrast, the modified model, which considers hysteresis and results in a trapped gas saturation of approximately 17%, shows a hydrogen recovery factor of 45% by the fourth cycle. Additionally, gas hysteresis has a notable impact on water production, with an observed 12.5% increase in volume in the model that incorporates gas hysteresis. Furthermore, optimization of the recovery process was conducted by evaluating different cushion gases such as CO₂, N₂, and CH₄, with the latter proving to be the optimal choice. These findings enhance the accuracy of estimating the H₂ recovery factor, which is crucial for assessing the feasibility of storage projects.

Summary: Numerical simulation of the CO2 storage process in porous media, such as in hydrocarbon (gas or oil) depleted reservoirs and in saline aquifers, has been the most indicated tool due to its ability to represent CO2 capacity and the different trapping mechanisms that retain CO2 in the subsurface. Given the complexity of the physicochemical phenomena involved, the modeling needs to incorporate multiphase flow, complex representation of fluids, rock, and rock-fluid interaction properties. These include CO2 reactions with aqueous species and with reservoir rock minerals, in addition to the structural and stratigraphic aspects of the reservoir heterogeneity. These phenomena need to be represented on suitable temporal and spatial scales for accurate predictions of their impacts. Currently, many studies are focused on simulating submodels or sectors of the reservoir, where using finer grids is still practical. This level of grid refinement can be prohibitive, in terms of simulation times, for modeling the entire reservoir. To address this challenge, we propose a new and practical workflow to simulate CO2 storage projects in large field-scale models. When the proposed workflow is applied in both synthetic and real field cases, simulation time is reduced by up to 96% compared to that of the fine-grid model, preserving the same results in representing the aforementioned mechanisms. The workflow is based on classical and standard approaches to handle the high simulation time, but in this study, they are structured and sequenced in three steps. The first one considers the most relevant mechanisms for CO2 storage, ranked from a high-resolution sector model. With the mechanisms prioritized in the previous step, a single-phase upscaling of petrophysical properties can be applied in the field-scale model, followed by adopting a grid with dynamic sizing. The proposed methodology is applied to saline aquifer models in this study, but it can be extended for storage in depleted hydrocarbon reservoirs.

In the future, there will be competition among natural gas, CO₂, and hydrogen for suitable geological storage sites. Therefore, it is crucial to evaluate all of the potential storage options. One promising option is the utilization of fractured carbonate rocks, which offer significant opportunities for gas sequestration in depleted reservoirs and saline aquifers. The objective of this study is to assess the feasibility of using carbonate matrix rocks in saline aquifers for carbon capture and storage (CCS) projects. Although carbonate reservoirs are currently not ranked highly for carbon storage due to the risk of CO₂ leakage, their matrix rock with reactive minerals like calcite and dolomite, along with the possibility of natural fractures, presents an interesting opportunity. This research proposes a reassessment of the role of fractures, which are typically viewed as a risk factor, within a novel and integrated context. It combines geochemical modeling with numerical models that incorporate two distinct density levels of natural fractures. The interactions between the carbonate matrix, the formation brine, and the injected CO₂ can lead to water vaporization and the deposition of evaporite minerals, known as the halite scale, within the porous medium. These minerals can be transported within highly conductive fractures that possess a permeability 100 times greater than the matrix. The study findings indicate that the fractures become filled, creating a natural seal that prevents CO₂ leakage through what was previously considered a potential pathway in both models and different initial pH values. Furthermore, the results demonstrate the formation of secondary minerals through the reaction of CO₂ and its aqueous counterparts with rock matrix minerals. These minerals, including Dawsonite, are then deposited within fracture apertures, compensating for the dissolution of calcite from the matrix and reducing the risk of enhanced fracture conductivity during CCS operations. The deposition of halite scales in initially acidic-brine saturated aquifers and/or Dawsonite scales in initially alkaline-brine saturated aquifers serves to partially counterbalance the permeability enhancement resulting from calcite dissolution. This phenomenon makes carbonate rocks a more secure option and highlights their potential suitability for CCS projects. The existence of these scales acts as a protective barrier, reducing the risk of increased permeability and enhancing the integrity of the storage reservoir.

This study used numerical simulations of CO₂ storage to identify the benefits of horizontal wells for geological carbon storage, such as enhancing CO₂ trapped in porous media due to relative permeability and capillary hysteresis. Two injection schemes were tested: one using a vertical injector and the other employing a horizontal well. The results revealed two main findings. Firstly, the horizontal injection well effectively prevented or minimized CO₂ penetration into the caprock across various sensitivity scenarios and over a thousand years of CO₂ redistribution. Secondly, horizontal wells provided a safe approach to trapping CO₂, increasing its entrapment as a residual phase by up to 19% within the storage site. This, in turn, reduced or prevented any unexpected events associated with CO₂ leakage through the caprock. Additionally, the paper proposes a practical method for designing the optimal length of a horizontal well. This method considers a combination of two parameters: the additional CO₂ that can be trapped using a horizontal well and the gravity number. In the case of the reservoir model of this study, a horizontal branch with a length of 2000 m was found to be the most effective design in enhancing CO₂ entrapment and reducing CO₂ buoyancy.

Hydrogen is a pivotal energy carrier for achieving sustainability and stability, but safe and efficient geological underground hydrogen storage (UHS) is critical for its large-scale application. This study investigates the impacts of geochemical and biochemical reactions on UHS, addressing challenges that threaten storage efficiency and safety. Geochemical reactions in saline aquifers, particularly the generation of hydrogen sulfide (H2S), were analyzed using advanced compositional and geochemical modeling calibrated with experimental kinetic data. The results indicate that geochemical reactions have a minimal effect on hydrogen consumption. However, by year 10 of storage operations, H₂S levels could reach 12–13 ppm, necessitating desulfurization to maintain storage performance and safety. The study also examines the methanogenesis reaction, where microorganisms consume hydrogen and carbon dioxide to produce methane. Numerical simulations reveal that microbial activity under suitable conditions can reduce in situ hydrogen volume by up to 50%, presenting a critical hurdle to UHS feasibility. These findings highlight the necessity of conducting microbial analyses of reservoir brines during the screening phase to mitigate hydrogen losses. The novelty of this work lies in its comprehensive field-scale analysis of impurity-induced geochemical and microbial reactions and their implications for underground hydrogen storage. By integrating kinetic parameters derived from experimental data with advanced computational modeling, this study uncovers the mechanisms driving these reactions and highlights their impact on storage efficiency, and safety. By offering a detailed field-scale perspective, the findings provide a pivotal framework for advancing future hydrogen storage projects and ensuring their practical viability.