Selective laser melting (SLM) has attracted increasing attention all over the world. As an important parameter, hatch spacing, which is the distance between scan lines, however, still needs a more systematic study. In this paper, the relationship between hatch spacing and mechanical properties, including microhardness, wear resistance, and porous density, was studied. The testing results revealed that when hatch spacing decreased, the overlapping rate increased which resulted in an increase in the convection in the molten pool. It led to the formation of pores in the molten pool. However, when hatch spacing was too large, the overlapping zone decreased, while the strength between each welding line was not strong enough. It caused a decrease in the quality of printed parts. Combined with the testing results gained in this work, it can be seen that a 0.06 mm hatch spacing was considered as a relatively optimal condition for part formation under 0.05 μm. Comparison of the morphology of the samples printed under different hatch spacing also confirmed the phenomenon observed here.
Limestone calcined clay cement (LC3) presents a promising alternative material due to its reduced CO2 emissions and superior mechanical properties compared to traditional Portland cement (PC). This study investigates the synergistic effect of calcined coal-series kaolinite (CCK) and limestone (LS) on the hydration behavior of cement, specifically focusing on varying mass ratios. The combination of CCK and LS promotes the formation of strätlingite and carboaluminates, which enhances early-age strength development. Additionally, the inclusion of CCK facilitates the formation of carboaluminates during later stages of hydration. After 56 days of hydration, the content of carboaluminates is over 10%wt. This stimulation of secondary hydration products significantly refines the evolution of pore structure, with the harmful large pores gradually transformed into harmless medium pores and gel pores, leading to marked improvements in compressive strength from 7 to 28 days. Replacing 45% PC with CCK and LS at mass ratio of 7 to 2, the compressive strength of blends reaches 47.2 MPa at 28 days. Overall, the synergistic interaction between CCK and LS presents unique opportunities to minimize the CO2 footprint of the cement industry without compromising early and long-term performance.
Iron ore tailings (IOTs) are byproducts of the iron mining industry that have gained significant attention in recent years due to their potential for comprehensive utilization. This study investigates how blending steel slag with IOTs (a siliceous raw material) instead of lime (a calcareous raw material) affects slurry foaming properties, mechanical properties, and reaction mechanisms of autoclaved aerated concrete (AAC). The results indicate that the sample containing 24% IOT content exhibited the best performance, with a bulk density of 640 kg/m3 and a compressive strength of 4.1 MPa. In addition, IOTs not only served as a filling material but also acted as a carrier for the growth of tobermorite. Tobermorite was combined with the unreacted iron tailing and its neighboring tobermorite to form a cohesive whole. This study provides valuable insights into the potential for IOTs to improve the properties of AAC when used as a supplementary material. The findings also suggest that the comprehensive utilization of IOTs and other industrial byproducts have the potential to contribute to the development of sustainable building materials and reduce the environmental impact of the mining industry.
22 December 2022 in Journal of the Indian Chemical Society