Rare earth Eu3+-doped nanoceria with an average size of 60 nm were synthesized by urea–nitrate solution combustion reaction. The microstructure and morphology of the samples were characterized by X-ray diffraction patterns (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (SEM). The host is confirmed to be pure CeO2. However, there are two distinct oxygen surroundings due to the substitution of Ce4+ species with Eu3+ ions. The optical properties of CeO2:Eu were investigated by photoluminescence and X-ray luminescence spectroscopy. The samples can be excited with 360 nm (ultra-violet light, the charge transfer band of O–Ce) and 466 nm (blue light, the Eu3+ 7F0 → 5D2 transition) respectively, and exhibit typical red-light emission of Eu3+. At low Eu3+ concentrations, the sample can be effectively excited with 360 nm. With the increase of the Eu3+ concentration, the dominant excitation wavelength is changed to 466 nm, which is beneficial for use in solid state lighting because of the coincidence with the emission of GaN chips. Under the excitation of 466 nm, the quenching concentration of Eu3+ can be increased to 16 mol% due to the interface effects of the nanoscale materials. Furthermore, the X-ray luminescence of CeO2:Eu also shows strong red-light emission, manifesting that the material is a promising scintillator for radiation detection.
22 January 2014 in Journal of Materials Chemistry C
Rare-earth Sm 3+ -activated nano/submicroscale ceria particles with suitable excitation wavelength, regular shape and strong luminescence have been prepared by PVA-assisted combustion synthesis, which is expected to meet the demands of solid state lighting.
6 January 2014 in Physical Chemistry Chemical Physics
A facile synthesis method was developed based on the seed-mediated growth to get the narrow dispersed silver nanoparticles with controllable sizes ranging from 20 nm to larger than 120 nm. Environmentally friendly glucose acts as a reducing agent. Because of its weak reducing ability, the secondary nucleation is prevented in the seed-mediated growth, and the size of silver nanoparticles can be tuned continuously by the continuous addition of reactants. Controlling the supersaturation level is critical to suppress both the nucleation and Ostwald ripening, which can be realized by carefully controlling the addition rate of the reactants. We also set up a convenient method to determine the size and size-distribution of silver nanoparticles from the size-dependent absorption spectra of the colloids, and optimize the growth parameters using this method to get narrow dispersed silver nanoparticles.