Nitrate contamination in stream water and groundwater is a serious environmental problem that arises in areas of high agricultural activities or high population density. It is therefore important to identify the source and flowpath of nitrate in water bodies. In recent decades, the dual isotope analysis (δ¹⁵N and δ¹⁸O) of nitrate has been widely applied to track contamination sources by taking advantage of the difference in nitrogen and oxygen isotope ratios for different sources. However, transformation processes of nitrogen compounds can change the isotopic composition of nitrate due to the various redox processes in the environment, which often makes it difficult to identify contaminant sources. To compensate for this, the stable water isotope of the H₂O itself can be used to interpret the complex hydrological and hydrochemical processes for the movement of nitrate contaminants. Therefore, the present study aims at understanding the fundamental background of stable water and nitrate isotope analysis, including isotope fractionation, analytical methods such as nitrate concentration from samples, instrumentation, and the typical ranges of δ¹⁵N and δ¹⁸O from various nitrate sources. In addition, we discuss hydrograph separation using the oxygen and hydrogen isotopes of water in combination with the nitrogen and oxygen isotopes of nitrate to understand the relative contributions of precipitation and groundwater to stream water. This study will assist in understanding the groundwater flowpaths as well as tracking the sources of nitrate contamination using the stable isotope analysis in combination with nitrate and water.

Groundwater salinization in coastal aquifers because of seawater intrusion has raised serious concerns worldwide since it deteriorates the quality of drinking water and thereby threatens sustainable economic development. In particular, this problem has been a cause of growing concern in the western coastal regions of South Korea. In this paper, we review studies of seawater intrusion in western coastal regions of South Korea conducted over the past 20 years, particularly focusing on studies reported in international journals. We summarize the study locations, methods used, and major findings from individual and regional-scale studies. General methods used to identify and interpret seawater intrusion and subsequent geochemical processes are also presented. On the basis of insights gleaned from the previous studies, future research needs are discussed.

This study evaluated the effects of CO₂ leakage on the geochemical composition of groundwater in various geological media through long-term column experiments. Four columns were set up with soil representing a silicate aquifer; clean sand; a sand and limestone mixture; and alluvium soil, respectively. The experiments were conducted under the same experimental conditions for approximately one year. As the CO₂-saturated synthetic groundwater was introduced into the columns, a decrease in pH and increases in electrical conductivity (EC), alkalinity, and concentrations of cations and trace elements were observed in all geological media. However, different patterns of changes were also observed depending on the mineralogical and physico-chemical characteristics of each material. As the column operation continued, while the pH decreased and low alkalinity values were more evident in the silicate soil and clean sand columns, the carbonate column continued to show high alkalinity and EC values in addition to high concentrations of most cations. The alluvium soil showed distinctive cation-exchange behaviors during the initial introduction of CO₂. The results indicate that changes in the geochemical composition of groundwater will depend on the characteristic of the geological medium such as pH buffering capacity and cation exchange capacity. This study can be useful for monitoring and managing the impacts of CO₂ leakage in various aquifer environments.