Laser cladding technology serves as a pivotal technique in industrial production, especially in the realms of additive manufacturing, surface enhancement, coating preparation, and the repair of part surfaces. This study investigates the influence of metal powder composition and processing parameters on laser cladding coatings utilizing the Taguchi orthogonal experimental design method. To optimize the laser cladding parameters, multi-response grey relational analysis (GRA) was employed, aiming to improve both the microhardness and the overall quality of the coatings. The optimal parameter combinations identified through GRA were subsequently validated through experimental tests. The results reveal that the microhardness and quality of the coatings are substantially influenced by several critical factors, including the powder feed rate, laser power, high-entropy alloy (HEA) addition rate, scanning speed, and substrate tilt angle. Specifically, the powder feed rate exerts the most significant effect on the microhardness, dilution rate, and average contact angle. In contrast, laser power primarily impacts the mean contact angle difference. The HEA addition rate notably affects the mean contact angle difference, while the scanning speed affects the microhardness and the substrate tilt angle influences the average contact angle. The results of the validation experiment showed a deviation of only 0.95% from the predicted values, underscoring the efficacy of the grey relational analysis (GRA) in optimizing the laser cladding process parameters. The methodology presented in this paper can be applied to determine the ideal processing parameters for multi-response laser cladding processes, encompassing applications such as surface peening and surface repair.

The low strength caused by the single FCC structure of the CrMnFeCoNi high entropy alloy (HEA) limits its application in the field of coating. Here, we prepared high-entropy alloy coatings of CrMnFeCoNi with different ZrC contents on Q235 steel by a plasma transferred arc process. The effects of ZrC on the microstructure and properties of the CrMnFeCoNi HEA coating were investigated by optical microscopy, scanning electron microscope, and X-ray diffraction and by employing a potensiostat/galvanostat. The results showed that ZrC mainly existed in the coatings as a second phase, having little influence on the main crystal structure and micromorphology of the CrMnFeCoNi HEA coating. The hardness of the CrMnFeCoNi HEA coating increased with the ZrC content. ZrC can effectively improve the corrosion resistance of the CrMnFeCoNi HEA coating. In a 1 mol/L NaCl solution with 4 wt% ZrC, the annual corrosion rate was only 5.997% of that of the HEA coating. Nevertheless, the improvement in the wear resistance of CrMnFeCoNi high-entropy alloy coatings was not apparent with the addition of ZrC. Consequently, the addition of ZrC to the FeCoCrNiMn high-entropy alloy coating holds promise for applications in corrosion resistance, particularly in oceanic environments.