Lubricants are materials able to reduce friction and/or wear of any type of moving surfaces facilitating smooth operations, maintaining reliable machine functions, and reducing risks of failures while contributing to energy savings. At present, most worldwide used lubricants are derived from crude oil. However, production, usage and disposal of these lubricants have significant impact on environment and health. Hence, there is a growing pressure to reduce demand of this sort of lubricants, which has fostered development and use of green lubricants, as vegetable oil-based lubricants (biolubricants). Despite the ecological benefits of producing/using biolubricants, availability of the required raw materials and agricultural land to create a reliable chain supply is still far from being established. Recently, biomass from some microalgae species has attracted attention due to their capacity to produce high-value lipids/oils for potential lubricants production. Thus, this multidisciplinary work reviews the main chemical-physical characteristics of lubricants and the main attempts and progress on microalgae biomass production for developing oils with pertinent lubricating properties. In addition, potential microalgae strains and chemical modifications to their oils to produce lubricants for different industrial applications are identified. Finally, a guide for microalgae oil selection based on its chemical composition for specific lubricant applications is provided.
The fully developed velocity distributions of a viscoplastic Carbopol microgel [0.12 wt. % poly(acrylic acid) in water] flowing axially in the annular gap between two long concentric cylinders were determined. The ratios of the length over the gap and the inner over the outer radii, κ, of the annulus were 442 and 0.78, respectively. The particle image velocimetry,PIV,measurements revealed that the viscoplasticity of the microgel in axial annular flow is manifested via the formation of plug flow and wall slip. The plug flow region spanned the entire or part of the annular gap depending on whether the absolute values of the shear stresses at the two walls were below or above the yield stress of the microgel, respectively. For all flow rates, the velocities at the two walls were similar indicating that the absolute values of the wall shear stress were also similar. Equality of the shear stresses at the two walls suggested that axial annular flow at a relatively high κ can be used as a viscometric flow for which the shear stresses at the two walls can be obtained directly from the fully developed pressure gradient and the annulus dimensions. The velocity distributions compared favorably with the predictions of the analytical solutions of the equation of motion for the axial annular flow of Herschel–Bulkley fluid subject to wall slip. The agreement between the experimental data and the predictions of the analytical model further validates the use of viscoplastic constitutive equations in conjunction with the wall slip condition for the analysis of steady and fully developed shear flows of viscoplastic fluids.