Stable self-assembled monolayers (SAMs), such as (2-(9H-carbazol-9-yl)) ethylphosphonic acid (2PACz), are crucial for reducing interfacial energy loss in high-performance perovskite solar cells (PSCs). However, the inherent aggregation tendency of SAMs at the buried interface hinders the device’s performance. Here, we propose a surfactant-assisted strategy to inhibit the aggregation of 2PACz by functionalizing cetyltrimethylammonium bromide (CTAB). Capitalizing on its distinctive electrostatic potential distribution, CTAB engages in non-bonding interactions with 2PACz. Theoretical and experimental characterizations prove that this promotes the uniform dispersion and anchoring of 2PACz on the substrate, leading to the SAM formation with high surface potential and excellent coverage. Moreover, the perovskite films with CTAB-modified SAM exhibit enhanced crystallinity with reduced trap state density and improved hole extraction efficiency. Consequently, the PSCs with a p-i-n architecture achieve a power conversion efficiency (PCE) of 26.20% (0.072 cm²). Scaled-up modules attain a PCE of 22.34% (22.96 cm²), confirming the scalability. Additionally, anti-aggregation-SAMs-integrated devices demonstrate stability, maintaining over 80% and 90% of their initial PCEs after tracking at maximum power point for 800 h and ageing at 65 °C for 1000 h, respectively.

The rapid development of wearable electronic products necessitates flexible and efficient energy storage solutions. Fiber-shaped supercapacitors (FSSCs) have gained significant attention as promising substitutes owing to their flexibility, low weight, and ability to integrate seamlessly into textile and wearable applications. This review offers an in-depth examination of the latest developments in FSSCs, distinguishing itself by not only summarizing diverse electrode materials such as carbon-based, polymer-based, and novel MXenes but also exploring their unique properties and applications in depth. We critically examine various fabrication techniques that enable the customization of fiber structures, including wet-spinning, electrostatic spinning, melt spinning, co-spinning, and advanced three-dimensional (3D) printing methods. Furthermore, we investigate innovative design strategies aimed at enhancing performance, such as film/sheet twisting for increased surface area and multilayer integrated designs. By discussing the integration of FSSCs into applications such as energy storage devices and sensors, we shed light on their potential to revolutionize the field. The review wraps up by identifying future challenges and directions, underlining the critical need for advancements in material synthesis, device design, and integration strategies. These advancements are crucial for the widespread adoption of FSSCs in flexible and wearable electronics. Continued research holds the potential to deliver next-generation energy storage solutions tailored to the growing demands of the wearable technology industry.