The current status of silver nanoparticles (AgNPs) in the water environment in Malaysia was examined and reported. For inspection, two rivers and two sewage treatment plants (STPs) were selected. Two activated carbons derived from oil palm (ACfOPS) and coconut (ACfCS) shells were proposed as the adsorbent to remove AgNPs. It was found that the concentrations of AgNPs in the rivers and STPs are in the ranges of 0.13 to 10.16 mg L⁻¹ and 0.13 to 20.02 mg L⁻¹, respectively, with the highest concentration measured in July. ACfOPS and ACfCS removed up to 99.6 and 99.9% of AgNPs, respectively, from the water. The interaction mechanism between AgNPs and the activated carbon surface employed in this work was mainly the electrostatic force interaction via binding Ag⁺ with O⁻ presented in the activated carbon to form AgO. Fifteen kinetic models were compared statistically to describe the removal of AgNPs. It was found that the experimental adsorption data can be best described using the mixed 1,2-order model. Therefore, this model has the potential to be a candidate for a general model to describe AgNPs adsorption using numerous materials, its validation of which has been confirmed with other material data from previous works.

The mismatch between freshwater demand and its availability is a major problem that causes global water scarcity. The exploration and utilization of rainwater seem to be viable options for minimizing the aforementioned issue. This manuscript reviews the prospects and challenges of the rainwater harvesting system (RWHS) in Malaysia. Malaysia can be categorized as a country that has high annual rainfall, as well as high domestic water consumption. Thus, Malaysia is well positioned to harvest rainwater for both potable and non-potable uses. Although the RWH guidelines were issued in Malaysia in 1999, the implementation of RWHS as an alternative water resource is still very limited due to its long return on investment and poor public acceptance. Major future challenges on the implementation of RWHS in Malaysia are to achieve competitive cost, the wide application of commercial buildings, a cost effective treatment system, effective policy implementation, the application of green materials, public perception improvement, and reliable first flush technology. Some recommendations such as providing appropriate subsidies and limiting the use of piped water are necessary for implementing RWHS at wider scales.