SnSe doped a different way: Heat can be converted into electricity by thermoelectric materials. Such materials are promising for use in solid-state cooling devices. A challenge for developing efficient thermoelectric materials is to ensure high electrical but low thermal conductivity. Chang et al. found that bromine doping of tin selenide (SnSe) does just this by maintaining low thermal conductivity in the out-of-plane direction of this layered material. The result is a promising n-type thermoelectric material with electrons as the charge carriers—an important step for developing thermoelectric devices from SnSe. Science , this issue p. 778

The relatively inferior performance of n-type legs impedes the application of PbTe materials in intermediate temperature thermoelectric devices. In order to elevate the thermoelectric properties of n-type PbTe, we added some Sb phases into 0.1% PbI₂-doped PbTe by a conventional melting method. Transmission electron microscopy (TEM) analysis together with density function theory (DFT) calculations showed that endotaxial Sb nanoprecipitates were produced in the PbTe samples at room temperature, and that part of these nanoprecipitates gradually dissolved into the PbTe matrix to form Sb_Pb–Sb_Te dual-site substitutional point defects as temperature increased. A maximum ZT of about 1.8 was achieved at 773 K for the n-type PbTe_0.998I_0.002–3%Sb composite due to a simultaneous improvement in power factor and reduction in lattice thermal conductivity. In the PbTe_0.998I_0.002–x%Sb (x = 1–4) composite samples, the Seebeck coefficient was much higher than that of the reported single-phase PbTe samples with similar carrier concentration, which mainly originated from distortion of the density-of-states caused by Sb dual-site doping. Simulations based on the Callaway model suggested that the Sb_Pb–Sb_Te dual-site substitutional point defects also played an important role in decreasing the lattice thermal conductivity at elevated temperature. We propose that the synergistic role of Sb in both electrical and thermal transport should be highly applicable in other bulk thermoelectric materials.