As the most abundant greenhouse gas in the atmosphere, CO₂ has a significant impact on climate change. Therefore, the determination of the temporal and spatial distribution of CO₂ is of great significance in climate research. However, existing CO₂ monitoring methods have great limitations, and it is difficult to obtain large-scale monitoring data with high spatial resolution, thus limiting the effective monitoring of carbon sources and sinks. To obtain complete Chinese daily-scale CO₂ information, we used OCO-2 XCO₂ data, Carbon Tracker XCO₂ data, and multivariate geographic data to build a model training data set, which was then combined with various machine learning models including Random Forest, Extreme Random Forest, XGBoost, LightGBM, and CatBoost. The results indicated that the Random Forest model presented the best performance, with a cross-validation R² of 0.878 and RMSE of 1.123 ppm. According to the final estimation results, in terms of spatial distribution, the highest multi-year average RF XCO₂ value was in East China (406.94 ± 0.65 ppm), while the lowest was in Northwest China (405.56 ± 1.43 ppm). In terms of time, from 2016 to 2018, the annual XCO₂ in China continued to increase, but the growth rate showed a downward trend. In terms of seasonal effects, the multi-year average XCO₂ was highest in spring (407.76 ± 1.72 ppm) and lowest in summer (403.15 ± 3.36ppm). Compared with the Carbon-Tracker data, the XCO₂ data set constructed in this study showed more detailed spatial changes, thus, can be effectively used to identify potentially important carbon sources and sinks.

High concentrations of ground-level ozone (O₃) pose a significant threat to human health. Obtaining high-spatiotemporal-resolution information about ground-level O₃ is of paramount importance for O₃ pollution control. However, the current monitoring methods have a lot of limitations. Ground-based monitoring falls short in providing extensive coverage, and remote sensing based on satellites is constrained by specific spectral bands, lacking sensitivity to ground-level O₃. To address this issue, we combined brightness temperature data from the Himawari-8 satellite with meteorological data and ground-based station data to train four machine learning models to obtain high-spatiotemporal-resolution information about ground-level O₃, including Categorical Boosting (CatBoost), eXtreme Gradient Boosting (XGBoost), Light Gradient Boosting Machine (LGBM), and Random Forest (RF). Among these, the CatBoost model exhibited superior performance, achieving a ten-fold cross-validation R² of 0.8534, an RMSE of 17.735 μg/m³, and an MAE of 12.6594 μg/m³. Furthermore, all the selected feature variables in our study positively influenced the model. Subsequently, we employed the CatBoost model to estimate averaged hourly ground-level O₃ concentrations at a 2 km resolution. The estimation results indicate a close relationship between ground-level O₃ concentrations and human activities and solar radiation.