The erosion of the accelerating chamber walls is one of the main factors limiting the operational life of Hall effect thrusters (HETs), and it is mainly related to the sputtering of ceramic walls due to the impacting energetic ion particles. The erosion phenomenon is investigated by means of a numerical model that couples the plasma model HYPICFLU2, used for evaluating the local distributions of ion energies and incidence angles, and a sputtering model specific for the xenon–Borosil pair, which is the most used in HETs application. The sputtering yield model is based on the measurements by Ranjan et al. that are improved with a linear factor to include wall temperature effect, recently studied by Parida et al. The experimental eroded profiles of SPT100 walls are selected as benchmark. The results show that there is a decrease in erosion speed with time, in accordance with experimental measurements, but the model underestimates, by about 50–60%, the erosion at the channel exit, which suggests a stronger dependence of sputter yield on surface temperature. Thus, the need for new experimental measurements of sputtering in the range of impact energy, angle, and wall temperature, respectively, of 10–250 eV, 0–85°, 30–600 °C, arises.