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Dehydrogenation processes play an important role in the petrochemical industry. High selectivity towards olefins is usually hindered by numerous side reactions in a conventional cracking/pyrolysis technology. Herein, we show recent studies devoted to selective ethylene production via oxidative and non-oxidative reactions. This review summarizes the progress that has been achieved with ethane conversion in terms of the process effectivity. Briefly, steam cracking, catalytic dehydrogenation, oxidative dehydrogenation (with CO2/O2), membrane technology, and chemical looping are reviewed.
Danis Fairuzov; Ilias Gerzeliev; Anton Maximov; Evgeny Naranov. Catalytic Dehydrogenation of Ethane: A Mini Review of Recent Advances and Perspective of Chemical Looping Technology. Catalysts 2021, 11, 833 .
AMA StyleDanis Fairuzov, Ilias Gerzeliev, Anton Maximov, Evgeny Naranov. Catalytic Dehydrogenation of Ethane: A Mini Review of Recent Advances and Perspective of Chemical Looping Technology. Catalysts. 2021; 11 (7):833.
Chicago/Turabian StyleDanis Fairuzov; Ilias Gerzeliev; Anton Maximov; Evgeny Naranov. 2021. "Catalytic Dehydrogenation of Ethane: A Mini Review of Recent Advances and Perspective of Chemical Looping Technology." Catalysts 11, no. 7: 833.
Zeolite-containing materials of various structural types (MFI, MEL, MTW) were prepared by the hydrothermal method using organic templates based on quaternary polymethylenediammonium salts. The materials were characterized by X-ray diffraction analysis, low-temperature nitrogen adsorption–desorption, temperature-programmed ammonia desorption, IR spectroscopy, scanning electron microscopy, X-ray fluorescence analysis, transmission electron microscopy, solid-state 27Al NMR spectroscopy, and IR spectroscopy of adsorbed pyridine. The effect of the template on the structure of the material obtained was revealed.
D. E. Tsaplin; E. R. Naranov; L. A. Kulikov; I. S. Levin; S. V. Egazar’Yants; A. L. Maximov; E. A. Karakhanov. Crystallization of Zeolites in the Presence of Diquaternary Alkylammonium Salts Derived from Dimethylethanolamine. Petroleum Chemistry 2021, 61, 815 -824.
AMA StyleD. E. Tsaplin, E. R. Naranov, L. A. Kulikov, I. S. Levin, S. V. Egazar’Yants, A. L. Maximov, E. A. Karakhanov. Crystallization of Zeolites in the Presence of Diquaternary Alkylammonium Salts Derived from Dimethylethanolamine. Petroleum Chemistry. 2021; 61 (8):815-824.
Chicago/Turabian StyleD. E. Tsaplin; E. R. Naranov; L. A. Kulikov; I. S. Levin; S. V. Egazar’Yants; A. L. Maximov; E. A. Karakhanov. 2021. "Crystallization of Zeolites in the Presence of Diquaternary Alkylammonium Salts Derived from Dimethylethanolamine." Petroleum Chemistry 61, no. 8: 815-824.
A series of micro-mesoporous materials with nanosponge structure were synthesized in accelerated mode. The influence of the perchlorate oxyanion promoter on the materials characteristics was thoroughly investigated. It was shown that the formation of nanosponge structure with high amount of promoter occurs through the consecutive steps that can be easily detected. The effect of promoter concentration on the crystalline structure was demonstrated under simple hydrothermal conditions. A novel hydrothermal method was developed to synthesize the micro-mesoporous materials with nanosponge structure in 18 h.
Evgeny R. Naranov; Alexey A. Sadovnikov; Aram L. Bugaev; Damir A. Shavaleev; Anton L. Maximov. A stepwise fabrication of MFI nanosheets in accelerated mode. Catalysis Today 2021, 378, 149 -157.
AMA StyleEvgeny R. Naranov, Alexey A. Sadovnikov, Aram L. Bugaev, Damir A. Shavaleev, Anton L. Maximov. A stepwise fabrication of MFI nanosheets in accelerated mode. Catalysis Today. 2021; 378 ():149-157.
Chicago/Turabian StyleEvgeny R. Naranov; Alexey A. Sadovnikov; Aram L. Bugaev; Damir A. Shavaleev; Anton L. Maximov. 2021. "A stepwise fabrication of MFI nanosheets in accelerated mode." Catalysis Today 378, no. : 149-157.
Non-phosphorous rhodium-containing catalysts for direct conversion of olefins to alcohols via tandem hydroformylation/hydrogenation have been designed and synthesized. Interaction between Rh(acac)(CO)2 and tertiary amino groups on the surface of mesoporous hybrid organic-inorganic supports yielded materials which were successfully used in the tandem process. Data obtained for a selected catalyst KN demonstrate that rhodium is in the Rh+1 state highly dispersed on the surface and is bonded with nitrogen atoms both before and after use. Evaluation of the catalytic performance shows high activity (hydroformylation TOF 312 h−1), chemoselectivity and stable hydroformylation yield at least in the first 5 cycles with a decrease in alcohol selectivity. The influence of temperature, reaction time, total pressure, and molar CO/H2 ratio of syngas on oxygenate yields is described. Type of the hydroformylation active sites and possible pathways for the observed decrease in hydrogenation are discussed.
Dmitry Gorbunov; Maria Nenasheva; Evgeny Naranov; Anton Maximov; Edward Rosenberg; Eduard Karakhanov. Tandem hydroformylation/hydrogenation over novel immobilized Rh-containing catalysts based on tertiary amine-functionalized hybrid inorganic-organic materials. Applied Catalysis A: General 2021, 623, 118266 .
AMA StyleDmitry Gorbunov, Maria Nenasheva, Evgeny Naranov, Anton Maximov, Edward Rosenberg, Eduard Karakhanov. Tandem hydroformylation/hydrogenation over novel immobilized Rh-containing catalysts based on tertiary amine-functionalized hybrid inorganic-organic materials. Applied Catalysis A: General. 2021; 623 ():118266.
Chicago/Turabian StyleDmitry Gorbunov; Maria Nenasheva; Evgeny Naranov; Anton Maximov; Edward Rosenberg; Eduard Karakhanov. 2021. "Tandem hydroformylation/hydrogenation over novel immobilized Rh-containing catalysts based on tertiary amine-functionalized hybrid inorganic-organic materials." Applied Catalysis A: General 623, no. : 118266.
Here we describe the development of a new mesocrytalline anatase-based photocatalyst with an activity nearly double that of the commercial Evonik Aeroxide® TiO2 P25 catalyst. An extensive characterization of this new catalytic material with XRD, TEM, SAED, EELS, SEM, RAMAN and XPS shows that its activity is promoted by its hybrid structure comprising mesocrystalline anatase and K2Ti6O13 whiskers formed within the TiO2 mesocrystals. This new and unexpected component is formed in situ within the TiO2 mesocrystalline framework at a surprisingly low temperature of 500 °C as a result of potassium diffusion from polymer-matrix phase. The growth of whiskers occurs at the 001 TiO2 planes of mesocrystals and their sizes attain 60 nm in a section and a few µm in length.
Alexey A. Sadovnikov; Alexey V. Garshev; Andrei A. Eliseev; Artemii N. Beltiukov; Evgeny R. Naranov; W. Li; Andrew J. Sutherland; Olga V. Boytsova. Nanowhiskers of K2Ti6O13 as a promoter of photocatalysis in anatase mesocrystals. Catalysis Today 2021, 378, 133 -139.
AMA StyleAlexey A. Sadovnikov, Alexey V. Garshev, Andrei A. Eliseev, Artemii N. Beltiukov, Evgeny R. Naranov, W. Li, Andrew J. Sutherland, Olga V. Boytsova. Nanowhiskers of K2Ti6O13 as a promoter of photocatalysis in anatase mesocrystals. Catalysis Today. 2021; 378 ():133-139.
Chicago/Turabian StyleAlexey A. Sadovnikov; Alexey V. Garshev; Andrei A. Eliseev; Artemii N. Beltiukov; Evgeny R. Naranov; W. Li; Andrew J. Sutherland; Olga V. Boytsova. 2021. "Nanowhiskers of K2Ti6O13 as a promoter of photocatalysis in anatase mesocrystals." Catalysis Today 378, no. : 133-139.
In this paper, we developed an effective method for purifying oil sludge using a sorbing electrochemical matrix and assessed the prospects of this method in comparison with conventional hydrocracking. We synthesized Ni-W supported hydrocracking catalysts with different morphology and studied their activity under various conditions, we compared the obtained catalysts with commercial catalyst SGK-5. We demonstrated that the introduction of a secondary mesoporous structure in the catalyst leads to an increase in the yield of light fractions to 52 wt.%. The possibility is demonstrated to obtain hydrocarbons from reservoir oil sludge, dispersed into an aqueous solution of detergent, by the method of low-temperature hydrogenation in sorbing electrochemical matrices. The obtained product was characterized by low viscosity, low content of transition metals (<320 ppm), and sulphur (<260 ppm).
Anton Maximov; Aslan Tsivadze; Alexander Fridman; Tatyana Kuchinskaya; Alexander Novikov; Maxim Shabanov; Evgeny Naranov. The Prospects for Processing Reservoir Oil Sludge into Hydrocarbons by Low-Temperature Hydrogenation in Sorbing Electrochemical Matrices in Comparison with Conventional High-Temperature Hydrocracking. Energies 2020, 13, 5362 .
AMA StyleAnton Maximov, Aslan Tsivadze, Alexander Fridman, Tatyana Kuchinskaya, Alexander Novikov, Maxim Shabanov, Evgeny Naranov. The Prospects for Processing Reservoir Oil Sludge into Hydrocarbons by Low-Temperature Hydrogenation in Sorbing Electrochemical Matrices in Comparison with Conventional High-Temperature Hydrocracking. Energies. 2020; 13 (20):5362.
Chicago/Turabian StyleAnton Maximov; Aslan Tsivadze; Alexander Fridman; Tatyana Kuchinskaya; Alexander Novikov; Maxim Shabanov; Evgeny Naranov. 2020. "The Prospects for Processing Reservoir Oil Sludge into Hydrocarbons by Low-Temperature Hydrogenation in Sorbing Electrochemical Matrices in Comparison with Conventional High-Temperature Hydrocracking." Energies 13, no. 20: 5362.
A multistage synthesis of the catalyst for the gas-phase alkylation of benzene with ethylene is implemented. A highly active catalyst is synthesized from zeolite ZSM-5 using thermal-vapor treatment. The obtained catalyst possesses an optimal acidity, which makes it possible to achieve a higher yield of ethylbenzene compared to the commercial catalyst based on ZSM-5 (88 and 62.7 wt %, respectively), an approximately equal ethylbenzene selectivity, and an almost three times lower concentration of the undesirable xylene impurity in an alkylate (0.004 and 0.011 wt %, respectively) in the gas-phase benzene alkylation with ethylene.
D. A. Shavaleev; M. L. Pavlov; R. A. Basimova; E. R. Naranov. Synthesis of a Zeolite-Containing Catalyst for Gas-Phase Alkylation of Benzene with Ethylene. Petroleum Chemistry 2020, 60, 1164 -1169.
AMA StyleD. A. Shavaleev, M. L. Pavlov, R. A. Basimova, E. R. Naranov. Synthesis of a Zeolite-Containing Catalyst for Gas-Phase Alkylation of Benzene with Ethylene. Petroleum Chemistry. 2020; 60 (10):1164-1169.
Chicago/Turabian StyleD. A. Shavaleev; M. L. Pavlov; R. A. Basimova; E. R. Naranov. 2020. "Synthesis of a Zeolite-Containing Catalyst for Gas-Phase Alkylation of Benzene with Ethylene." Petroleum Chemistry 60, no. 10: 1164-1169.
Highly efficient binder-free catalysts, based on zeolite Y, for the liquid-phase alkylation of benzene with ethylene have been synthesized. The catalysts have been modified by treating with aqueous solutions of hydrochloric and citric acids to remove extra-framework aluminum formed during the partial dealumination of zeolite Y. The synthesized catalysts have been tested in the alkylation of benzene with ethylene at a temperature of 200°C, a pressure of 2.5 MPa, a benzene : ethylene molar ratio of 5 : 1, and a benzene feed space velocity of 5 h−1. Over the modified catalyst, the ethylbenzene (EB) content in the alkylate increases by 27% and the EB selectivity increases by 5% compared to the initial Y zeolite.
D. A. Shavaleev; M. L. Pavlov; R. A. Basimova; A. A. Sadovnikov; V. V. Sudin; E. M. Smirnova; N. R. Demikhova; Yu. V. Grigor’Ev; A. L. Maksimov; E. R. Naranov. Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene. Petroleum Chemistry 2020, 60, 1073 -1079.
AMA StyleD. A. Shavaleev, M. L. Pavlov, R. A. Basimova, A. A. Sadovnikov, V. V. Sudin, E. M. Smirnova, N. R. Demikhova, Yu. V. Grigor’Ev, A. L. Maksimov, E. R. Naranov. Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene. Petroleum Chemistry. 2020; 60 (9):1073-1079.
Chicago/Turabian StyleD. A. Shavaleev; M. L. Pavlov; R. A. Basimova; A. A. Sadovnikov; V. V. Sudin; E. M. Smirnova; N. R. Demikhova; Yu. V. Grigor’Ev; A. L. Maksimov; E. R. Naranov. 2020. "Synthesis of Modified Catalyst for Liquid Phase Alkylation of Benzene with Ethylene." Petroleum Chemistry 60, no. 9: 1073-1079.
As- and Cl-containing impurities are highly detrimental to sulfided catalysts in hydrotreating processes. To prevent the irreversible loss of activity of the main sulfide catalysts by As and Cl contaminants, a protective double-layered guard bed catalyst is applied. Two types of mesoporous silica supports (SBA-15 and MCF) were used to obtain sorption-catalytic materials. The high specific surface area of the supports allowed for a significant increase in access to the active catalyst centers. The NiMo/SBA-15/Al2O3 and NiMg/MCF/Al2O3 sorption-catalytic materials demonstrated high activity and stability over 48 h for the simultaneous removal of As and Cl. The catalytic materials allowed for reducing the concentrations of As and Cl to less than 0.1 ppm in the diesel fraction under the following conditions: 5.0 MPa pressure, 2.0 h-1 LHSV, 300 L/L H2-to-substrate volume ratio, and 360 °C.
Evgeny Naranov; Oleg Golubev; Konstantin Zanaveskin; Alena Guseva; Pavel Nikulshin; Yury Kolyagin; Anton Maximov; Eduard Karakhanov. Ni-Based Nanoparticles on Mesoporous Silica Supports for Single-Stage Arsenic and Chlorine Removal during Diesel Fraction Hydrotreating. ACS Omega 2020, 5, 6611 -6618.
AMA StyleEvgeny Naranov, Oleg Golubev, Konstantin Zanaveskin, Alena Guseva, Pavel Nikulshin, Yury Kolyagin, Anton Maximov, Eduard Karakhanov. Ni-Based Nanoparticles on Mesoporous Silica Supports for Single-Stage Arsenic and Chlorine Removal during Diesel Fraction Hydrotreating. ACS Omega. 2020; 5 (12):6611-6618.
Chicago/Turabian StyleEvgeny Naranov; Oleg Golubev; Konstantin Zanaveskin; Alena Guseva; Pavel Nikulshin; Yury Kolyagin; Anton Maximov; Eduard Karakhanov. 2020. "Ni-Based Nanoparticles on Mesoporous Silica Supports for Single-Stage Arsenic and Chlorine Removal during Diesel Fraction Hydrotreating." ACS Omega 5, no. 12: 6611-6618.
The mechanism of MFI zeolite nanosheet formation was established under accelerated conditions using perchlorate ions and fresh zeolite seeds as promoters.
Evgeny R. Naranov; Alexey A. Sadovnikov; Ivan M. Vatsouro; Anton L. Maximov. The mechanism of promoter-induced zeolite nanosheet crystallization under hydrothermal and microwave irradiation conditions. Inorganic Chemistry Frontiers 2020, 7, 1400 -1410.
AMA StyleEvgeny R. Naranov, Alexey A. Sadovnikov, Ivan M. Vatsouro, Anton L. Maximov. The mechanism of promoter-induced zeolite nanosheet crystallization under hydrothermal and microwave irradiation conditions. Inorganic Chemistry Frontiers. 2020; 7 (6):1400-1410.
Chicago/Turabian StyleEvgeny R. Naranov; Alexey A. Sadovnikov; Ivan M. Vatsouro; Anton L. Maximov. 2020. "The mechanism of promoter-induced zeolite nanosheet crystallization under hydrothermal and microwave irradiation conditions." Inorganic Chemistry Frontiers 7, no. 6: 1400-1410.
The problems of zeolite catalysis associated with the introduction of domestic technologies are considered. Particular attention is paid to works related to the use of alternative components of catalytic systems, the introduction of new environmentally friendly materials that improve the quality of the fuels produced with their use. The processes of catalytic cracking, processing of heavy petroleum residues, solid-acid alkylation, and synthesis of light olefins and the problems of renewable feedstock processing are discussed in detail.
E. R. Naranov; K. I. Dement’Ev; I. M. Gerzeliev; N. V. Kolesnichenko; E. A. Roldugina; A. L. Maksimov. The Role of Zeolite Catalysis in Modern Petroleum Refining: Contribution from Domestic Technologies. Petroleum Chemistry 2019, 59, 247 -261.
AMA StyleE. R. Naranov, K. I. Dement’Ev, I. M. Gerzeliev, N. V. Kolesnichenko, E. A. Roldugina, A. L. Maksimov. The Role of Zeolite Catalysis in Modern Petroleum Refining: Contribution from Domestic Technologies. Petroleum Chemistry. 2019; 59 (3):247-261.
Chicago/Turabian StyleE. R. Naranov; K. I. Dement’Ev; I. M. Gerzeliev; N. V. Kolesnichenko; E. A. Roldugina; A. L. Maksimov. 2019. "The Role of Zeolite Catalysis in Modern Petroleum Refining: Contribution from Domestic Technologies." Petroleum Chemistry 59, no. 3: 247-261.
Process of chlorine removal from middle distillates with catalysts based on mesoporous materials was examined. The physicochemical characteristics of supports and catalysts based on SBA-15, Al-TUD, and MCF materials were compared. It was found that the catalyst based on MCF material can diminish the content of chlorine in a light diesel fraction to below 0.3 mg kg–1 at 360°C, pressure of 5.0 MPa, and LHSV of 2.0 h–1.
Oleg Golubev; S. V. Egazar’Yants; D. V. Matevosyan; Evgeny Naranov; A. L. Maksimov; E. A. Karakhanov. Development of Protective-Layer Catalysts for Removal of Chlorine Compounds from Diesel Fractions. Russian Journal of Applied Chemistry 2018, 91, 2040 -2045.
AMA StyleOleg Golubev, S. V. Egazar’Yants, D. V. Matevosyan, Evgeny Naranov, A. L. Maksimov, E. A. Karakhanov. Development of Protective-Layer Catalysts for Removal of Chlorine Compounds from Diesel Fractions. Russian Journal of Applied Chemistry. 2018; 91 (12):2040-2045.
Chicago/Turabian StyleOleg Golubev; S. V. Egazar’Yants; D. V. Matevosyan; Evgeny Naranov; A. L. Maksimov; E. A. Karakhanov. 2018. "Development of Protective-Layer Catalysts for Removal of Chlorine Compounds from Diesel Fractions." Russian Journal of Applied Chemistry 91, no. 12: 2040-2045.
Efficiency of various compositions of demetallization catalysts was studied in hydrodesulfurization of heavy crude oil. It was shown that the highest activity is observed for trimetallic NiCoMo systems, including those prepared with the use of heteropoly compounds. The influence exerted by introduction of up to 3 wt % ultrastable zeolite Y into the demetallization catalyst support on the activity in hydrodesulfurization reactions was examined. It was shown that addition of this zeolite makes it possible to reduce the content of sulfur in the reaction products, compared with the alumina support, and to preserve a high activity on raising the space velocity of feed.
R. E. Boldushevskii; Alena Guseva; N. Ya. Vinogradova; Evgeny Naranov; A. L. Maksimov; P. A. Nikul’Shin. Evaluation of the Hydrodesulfurization Activity in Development of Catalysts for Demetallization of Heavy Petroleum Feedstock. Russian Journal of Applied Chemistry 2018, 91, 2046 -2051.
AMA StyleR. E. Boldushevskii, Alena Guseva, N. Ya. Vinogradova, Evgeny Naranov, A. L. Maksimov, P. A. Nikul’Shin. Evaluation of the Hydrodesulfurization Activity in Development of Catalysts for Demetallization of Heavy Petroleum Feedstock. Russian Journal of Applied Chemistry. 2018; 91 (12):2046-2051.
Chicago/Turabian StyleR. E. Boldushevskii; Alena Guseva; N. Ya. Vinogradova; Evgeny Naranov; A. L. Maksimov; P. A. Nikul’Shin. 2018. "Evaluation of the Hydrodesulfurization Activity in Development of Catalysts for Demetallization of Heavy Petroleum Feedstock." Russian Journal of Applied Chemistry 91, no. 12: 2046-2051.
A series of Ru-contained catalysts based on mesoporous and micro-mesoporous supports synthesized for the selective hydrogenation of naphthalene and tetralin in n-hexadecane solution. The influence of the support – HMS, SBA-15 and ZSM-5/MCM-41, namely porous structure and acidity on the catalysts activity were thoroughly investigated. It was found that the supports acidity has a diminutive effect on the cis-decalin formation due to increased isomerization activity of cis-decalin to trans-decalin. It was shown that the amount of unconverted tetralin influenced the final cis/trans decalines ratio considerably. The effect of parameters such as temperature, hydrogen pressure and reaction time on conversion and selectivity to partially or fully hydrogenated products was investigated under 3-7 MPa H2, 220-320 °C and 0.5-3 h. It provides a practically fully naphthalene conversion and a high cis-decalin selectivity.
Evgeny R. Naranov; Anton Maximov. Selective conversion of aromatics into cis-isomers of naphthenes using Ru catalysts based on the supports of different nature. Catalysis Today 2018, 329, 94 -101.
AMA StyleEvgeny R. Naranov, Anton Maximov. Selective conversion of aromatics into cis-isomers of naphthenes using Ru catalysts based on the supports of different nature. Catalysis Today. 2018; 329 ():94-101.
Chicago/Turabian StyleEvgeny R. Naranov; Anton Maximov. 2018. "Selective conversion of aromatics into cis-isomers of naphthenes using Ru catalysts based on the supports of different nature." Catalysis Today 329, no. : 94-101.
Possibility of using mesoporous materials for obtaining Ni–Mo sorption-catalytic materials for purification of medium-distillate fractions to remove arsenic-containing compounds was examined. It was shown that, in the course of hydropurification, the acidity of the mesoporous material does not directly affect the extent to which the amount of arsenic in hydrocarbons is diminished. It was found that mesoporous supports of the SBA-15, TUD, and MCF types reduce the content of arsenic to less than 0.5 ppm at 360°C and 50 atm of H2.
E. R. Naranov; V. O. Samoilov; O. V. Golubev; K. L. Zanaveskin; A. L. Maksimov; E. A. Karakhanov. Development of Ni–Mo Sorption-Catalytic Materials for Removing Arsenic Compounds from Middle Distillates. Russian Journal of Applied Chemistry 2018, 91, 1688 -1693.
AMA StyleE. R. Naranov, V. O. Samoilov, O. V. Golubev, K. L. Zanaveskin, A. L. Maksimov, E. A. Karakhanov. Development of Ni–Mo Sorption-Catalytic Materials for Removing Arsenic Compounds from Middle Distillates. Russian Journal of Applied Chemistry. 2018; 91 (10):1688-1693.
Chicago/Turabian StyleE. R. Naranov; V. O. Samoilov; O. V. Golubev; K. L. Zanaveskin; A. L. Maksimov; E. A. Karakhanov. 2018. "Development of Ni–Mo Sorption-Catalytic Materials for Removing Arsenic Compounds from Middle Distillates." Russian Journal of Applied Chemistry 91, no. 10: 1688-1693.
Evgeny R. Naranov; Alexey A. Sadovnikov; Anton L. Maximov; Eduard A. Karakhanov. Development of micro-mesoporous materials with lamellar structure as the support of NiW catalysts. Microporous and Mesoporous Materials 2018, 263, 150 -157.
AMA StyleEvgeny R. Naranov, Alexey A. Sadovnikov, Anton L. Maximov, Eduard A. Karakhanov. Development of micro-mesoporous materials with lamellar structure as the support of NiW catalysts. Microporous and Mesoporous Materials. 2018; 263 ():150-157.
Chicago/Turabian StyleEvgeny R. Naranov; Alexey A. Sadovnikov; Anton L. Maximov; Eduard A. Karakhanov. 2018. "Development of micro-mesoporous materials with lamellar structure as the support of NiW catalysts." Microporous and Mesoporous Materials 263, no. : 150-157.
E.A. Roldugina; Evgeny Naranov; Anton Maximov; E.A. Karakhanov. Hydrodeoxygenation of guaiacol as a model compound of bio-oil in methanol over mesoporous noble metal catalysts. Applied Catalysis A: General 2018, 553, 24 -35.
AMA StyleE.A. Roldugina, Evgeny Naranov, Anton Maximov, E.A. Karakhanov. Hydrodeoxygenation of guaiacol as a model compound of bio-oil in methanol over mesoporous noble metal catalysts. Applied Catalysis A: General. 2018; 553 ():24-35.
Chicago/Turabian StyleE.A. Roldugina; Evgeny Naranov; Anton Maximov; E.A. Karakhanov. 2018. "Hydrodeoxygenation of guaiacol as a model compound of bio-oil in methanol over mesoporous noble metal catalysts." Applied Catalysis A: General 553, no. : 24-35.
The effect of the impregnation stage on the synthesis of NiW sulfide catalysts supported on the ZSM-5 zeolite has been studied. The hydrodearomatization (HDA) of light cycle oil (LCO) in the presence of a catalyst containing nickel and tungsten sulfides as an active phase impregnated onto a micro/mesoporous ZSM-5/SBA-15 support has been conducted. The catalyst has been compared with a commercial AGKD-400 diesel hydrotreating catalyst. It has been found that the impregnation of the supports with a solution containing an oxalic acid additive leads to an improvement in the morphology and composition of the active phase. The deepest hydrogenation is observed at 360°C, 6 MPa H2, and a LHSV = 0.5 h–1. The amount of diaromatic hydrocarbons decreases 12-fold, and the sulfur content decreases by 90%.
Evgeny Naranov; Oleg Golubev; Alena Guseva; P. A. Nikulshin; A. L. Maksimov; E. A. Karakhanov. Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates. Petroleum Chemistry 2017, 57, 1151 -1155.
AMA StyleEvgeny Naranov, Oleg Golubev, Alena Guseva, P. A. Nikulshin, A. L. Maksimov, E. A. Karakhanov. Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates. Petroleum Chemistry. 2017; 57 (12):1151-1155.
Chicago/Turabian StyleEvgeny Naranov; Oleg Golubev; Alena Guseva; P. A. Nikulshin; A. L. Maksimov; E. A. Karakhanov. 2017. "Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates." Petroleum Chemistry 57, no. 12: 1151-1155.
Evgeny Naranov; A. S. Badeeva; A. A. Sadovnikov; S. V. Kardashev; A. L. Maksimov; S. V. Lysenko; Vladimir Vinokurov; E. A. Karakhanov. Hydrogenation of aromatic hydrocarbons over nickel–tungsten sulfide catalysts containing mesoporous aluminosilicates of different nature. Petroleum Chemistry 2016, 56, 599 -606.
AMA StyleEvgeny Naranov, A. S. Badeeva, A. A. Sadovnikov, S. V. Kardashev, A. L. Maksimov, S. V. Lysenko, Vladimir Vinokurov, E. A. Karakhanov. Hydrogenation of aromatic hydrocarbons over nickel–tungsten sulfide catalysts containing mesoporous aluminosilicates of different nature. Petroleum Chemistry. 2016; 56 (7):599-606.
Chicago/Turabian StyleEvgeny Naranov; A. S. Badeeva; A. A. Sadovnikov; S. V. Kardashev; A. L. Maksimov; S. V. Lysenko; Vladimir Vinokurov; E. A. Karakhanov. 2016. "Hydrogenation of aromatic hydrocarbons over nickel–tungsten sulfide catalysts containing mesoporous aluminosilicates of different nature." Petroleum Chemistry 56, no. 7: 599-606.
Amy L. Miller; Michael Bowker; Andrés García-Trenco; Joseph Socci; Nia Richards; Graham Hutchings; Nicola Collis; James Earley; Simon Freakley; Robbie Burch; Mark Howard; Elad Gross; Andrzej Kotarba; Miron V. Landau; James Anderson; Bert Weckhuysen; Simon Kondrat; Evgeny Naranov; John Mark Douthwaite; Ram Tiruvalam; Sarwat Iqbal; Luke Parker; Parag Shah; Ewa Nowicka; Wataru Ueda; Alessandro Piovano; Philip Landon; Nico Fischer; Christian Reece; Bruce Gates; Michael Lamb; Eoin Jackman; Tomasz Jakubek; Avelino Corma; Michael Claeys; Henrik Svengren; Cynthia Friend; David Lennon; Joshua Makepeace; Hazel Hunter; Haresh Manyar. Application of novel catalysts: general discussion. Faraday Discussions 2016, 188, 399 -426.
AMA StyleAmy L. Miller, Michael Bowker, Andrés García-Trenco, Joseph Socci, Nia Richards, Graham Hutchings, Nicola Collis, James Earley, Simon Freakley, Robbie Burch, Mark Howard, Elad Gross, Andrzej Kotarba, Miron V. Landau, James Anderson, Bert Weckhuysen, Simon Kondrat, Evgeny Naranov, John Mark Douthwaite, Ram Tiruvalam, Sarwat Iqbal, Luke Parker, Parag Shah, Ewa Nowicka, Wataru Ueda, Alessandro Piovano, Philip Landon, Nico Fischer, Christian Reece, Bruce Gates, Michael Lamb, Eoin Jackman, Tomasz Jakubek, Avelino Corma, Michael Claeys, Henrik Svengren, Cynthia Friend, David Lennon, Joshua Makepeace, Hazel Hunter, Haresh Manyar. Application of novel catalysts: general discussion. Faraday Discussions. 2016; 188 ():399-426.
Chicago/Turabian StyleAmy L. Miller; Michael Bowker; Andrés García-Trenco; Joseph Socci; Nia Richards; Graham Hutchings; Nicola Collis; James Earley; Simon Freakley; Robbie Burch; Mark Howard; Elad Gross; Andrzej Kotarba; Miron V. Landau; James Anderson; Bert Weckhuysen; Simon Kondrat; Evgeny Naranov; John Mark Douthwaite; Ram Tiruvalam; Sarwat Iqbal; Luke Parker; Parag Shah; Ewa Nowicka; Wataru Ueda; Alessandro Piovano; Philip Landon; Nico Fischer; Christian Reece; Bruce Gates; Michael Lamb; Eoin Jackman; Tomasz Jakubek; Avelino Corma; Michael Claeys; Henrik Svengren; Cynthia Friend; David Lennon; Joshua Makepeace; Hazel Hunter; Haresh Manyar. 2016. "Application of novel catalysts: general discussion." Faraday Discussions 188, no. : 399-426.