The effect of the reduction method to prepare reduced graphene oxide (rGO) on the melt linear viscoelastic properties, electrical conductivity, polymer matrix crystalline behavior and dielectric properties of PEO-rGO nanocomposites was investigated. Reduction was performed chemically with either sodium borohydride (NaBH₄) or hydrazine monohydrate (N₂H₄·H₂O) or both reduction agents consecutively as well as thermally at 1000 °C. The different reduction methods resulted in exfoliated rGO sheets with different types and amounts of remaining functional groups, as indicated by FT-IR, Raman, TGA and XRD characterization. Moreover, their electrical conductivity ranged between 10⁻⁴ and 10⁻¹ S/cm, with the consecutive use of both chemical reduction agents being far superior. PEO nanocomposites with filler loadings of 0.5 wt %, 1 wt % and 2 wt % were prepared by solvent mixing. The rGO fillers affected the melt linear viscoelastic and crystalline behavior of the PEO matrix and resulted in nanocomposites with a substantially increased electrical conductivity. Despite the wide variability in filler conductivity, the effects on the polymer nanocomposite properties were less distinctive. A correlation was obtained between the reduction of the mobility of the polymer chains (evaluated by the glass transition temperature) and the dielectric strength of the interfacial polarisation originating from the effective entrapment of GO/rGO filler charges at the interface with the less conductive PEO. Thus, favorable interactions of the polar PEO with the filler led to reduced mobility of the PEO chains and thereby a more effective entrapment of the filler charges at the PEO interface.

The formulation of a high dielectric permittivity ceramic/polymer composite feedstock for daylight vat photopolymerization 3D printing (3DP) is demonstrated, targeting 3DP of devices for microwave and THz applications. The precursor is composed of a commercial visible light photo-reactive polymer (VIS-curable photopolymer) and dispersed titanium dioxide (TiO₂, TO) ceramic nano-powder or calcium copper titanate (CCT) micro-powder. To provide consistent 3DP processing from the formulated feedstocks, the carefully chosen dispersant performed the double function of adjusting the overall viscosity of the photopolymer and provided good matrix-to-filler bonding. Depending on the ceramic powder content, the optimal viscosities for reproducible 3DP with resolution better than 100 µm were η_(TO) = 1.20 ± 0.02 Pa.s and η_(CCT) = 0.72 ± 0.05 Pa.s for 20% w/v TO/resin and 20% w/v CCT/resin composites at 0.1 s⁻¹ respectively, thus showing a significant dependence of the “printability” on the dispersed particle sizes. The complex dielectric properties of the as-3D printed samples from pure commercial photopolymer and the bespoke ceramic/photopolymer mixes are investigated at 2.5 GHz, 5 GHz, and in the 12–18 GHz frequency range. The results show that the addition of 20% w/v of TO and CCT ceramic powder to the initial photopolymer increased the real part of the permittivity of the 3DP composites from ε’ = 2.7 ± 0.02 to ε’_(TO) = 3.88 ± 0.02 and ε’_(CCT) = 3.5 ± 0.02 respectively. The present work can be used as a guideline for high-resolution 3DP of structures possessing high-ε.

An investigation on antenna solutions for expendable origami paper flapping robots is presented. An origami flapping robotic bird that can be produced using standard A4 paper is employed. Antennas resonating at the two commonly used frequency bands, 2.4 GHz and 5.2 GHz, are designed for the limited space available on the folded origami structure. Two developments of the same dual-band monopole antenna are discussed. The first antenna is located on the robot’s spine and the second on its tail. A space diversity configuration is also studied. The antennas are printed directly onto a photo paper substrate and then folded into an origami robotic crane’s body structure. An ordinary desktop inkjet printer fitted with silver nanoparticle conductive ink cartridges has been employed. CST Microwave StudioTM has been used to design the antennas. A good agreement between the measured and simulated S11 results is achieved with a reasonable –10dB impedance bandwidth realized in the three cases studied. The radiation patterns are omnidirectional in the XZ plane which is desirable for the specific application. The diversity configuration has a mutual coupling of <–23dB and a gain of 1.4 dB and 2.8 dB at 2.4 GHz and 5.2 GHz respectively. The aim is to provide a new vision for antennas embedded into expandable flying robots based on traditional origami structures.

Nanocomposites based on Cu-doped nickel zinc ferrite and lead zirconium titanate exhibited significant microwave absorbing properties in the X-band (8.212.4GHz) region. Coprecipitation and homogeneous precipitation methods were utilized to synthesize Cu-doped nickel zinc ferrite (Cu0.2Ni0.4Zn0.4Fe2O4) and lead zirconium titanate (Pb(Zr0.52Ti0.48)O3) nanoparticles, respectively. To develop nanocomposites, dispersion of these nanoparticles into epoxy resin (LY665) polymeric matrix was carried out by using mechanical stirrer. Phase analyses of the nanoparticles were done by X-ray diffraction (XRD). Moreover, morphological characterization was done by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Energy dispersive X-ray spectroscopy (EDS) confirmed the chemical constituents present in the nanocomposites. Complex relative permittivity and complex relative permeability values of the nanocomposites were measured in different microwave frequencies in the X-band (8.212.4GHz) region by employing vector network analyzer (model PNA E8364B), and return loss (dB) values were calculated to identify the microwave absorbing performance of the present nanocomposites. Brilliant microwave absorbing properties have been achieved by the nanocomposites with the minimum return loss of 49.53dB at 8.44GHz when sample thickness was 3mm. For the present nanocomposites, mainly dielectric loss was responsible for loss mechanism.