A study of optical properties of ${\mathrm{Nd}}^{\text{3+}}$ doped oxyfluoride glasses and glass ceramics prepared by three different methods has been carried out. These methods start from ${\mathrm{NdF}}_3,$ ${\mathrm{Nd}}_2{\mathrm{O}}_3,$ or a ${\mathrm{Nd}}^{\text{3+}}$ ion solution as doping agent. The alternative preparation method based on a preliminary dissolution of the ${\mathrm{Nd}}^{\text{3+}}$ ions is proposed in order to avoid nonhomogeneous dopant distribution and spontaneous devitrification during glass elaboration. In the frame of the Judd–Ofelt theory, main radiative parameters have been studied: transition probabilities, lifetimes, and stimulated emission cross sections. Fluorescence decay curves have been also analyzed in order to study the final distribution of the ${\mathrm{Nd}}^{\text{3+}}$ ions after the ceramming process, discerning between ions that reside in the fluoride nanocrystals precipitated during heat treatment and those remaining in the glassy phase. The ${\mathrm{NdF}}_3$ based glass ceramics present the best values for spectroscopic parameters as the stimulated cross section of the ${}^4{F}_{\text{3/2}}{\to }^4{I}_{\text{11/2}}$ laser transition.

A novel Y_3(1−x)Er_3xGa₅O₁₂ nanocrystalline garnet has been synthesized by a sol–gel technique and a complete structural, morphological, vibrational, and optical characterization has been carried out in order to correlate the local structure of the Er³⁺ ions with their optical properties. The synthesized nanocrystals are found in a single-phase garnet structure with an average grain size of around 60 nm. The good crystalline quality of the garnet structure is confirmed by FTIR and Raman measurements, since the phonon modes of the nano-garnet are similar to those found in the single crystal garnet. Under blue laser excitation, intense green and red visible and 1.5 μm infrared luminescences are observed, whose relative intensities are very sensitive to the Er³⁺ concentration. The dynamics of these emissions under pulsed laser excitations are analyzed in the framework of different energy transfer interactions. Intense visible upconverted luminescence can be clearly observed by the naked eye for all synthesized Er³⁺-doped Y₃Ga₅O₁₂ nano-garnets under a cw 790 nm laser excitation. The power dependency and the dynamics of the upconverted luminescence confirm the existence of different two-photon upconversion processes for the green and red emissions that strongly depend on the Er³⁺ concentration, showing the potential of these nano-garnets as excellent candidates for developing new optical devices.

Optical properties of ${\mathrm{Eu}}^{\text{3+}}$ ions in oxyfluoride glass ceramics and in the precursor glasses (30 ${\mathrm{SiO}}_2,$ 15 ${\mathrm{Al}}_{\mathrm{2}}{\mathrm{O}}_3,$ 29 ${\mathrm{CdF}}_2,$ 22 ${\mathrm{PbF}}_2,$ 1.5 ${\mathrm{YF}}_3,$ and 2.5 ${\mathrm{EuF}}_3,$ in mol %) have been analyzed and compared. The ${\mathrm{Eu}}^{\text{3+}}$ ions in the glass ceramics are incorporated into a crystalline environment with higher symmetry and lower energy coupled phonons. Emission measurements indicate that this crystalline phase is ${\mathrm{EuF}}_3,$ instead of ${\mathrm{Pb}}_x{\mathrm{Cd}}_{\text{1−x}}{\mathrm{F}}_2$ as generally considered.