By analyzing phonon dispersion, we have evaluated the average Young’s modulus and Poisson’s ratio in graphite and in graphene grown on Ru(0001), Pt(111), Ir(111), Ni(111), and BC₃/NbB₂(0001). In both flat and corrugated graphene sheets and in graphite, we find a Poisson’s ratio of 0.19 and a Young’s modulus of 342 N/m. The unique exception is graphene/Ni(111), for which we find different values because of the stretching of C-C bonds occurring in the commensurate overstructure (0.36 and 310 N/m for the Poisson’s ratio and Young’s modulus, respectively). Such findings are in excellent agreement with calculations performed for a free-standing graphene membrane. The high crystalline quality of graphene grown on metal substrates leads to macroscopic samples with high tensile strength and bending flexibility for use in technological applications such as electromechanical devices and carbon-fiber reinforcements.

The plasmonic excitation of graphene (intraband and interband plasmons) and the composite modes formed by plasmons with other quasi-particles are reviewed.

The ability to convert light into an electrical signal with high efficiencies and controllable dynamics, is a major need in photonics and optoelectronics. In the Terahertz (THz) frequency range, with its exceptional application possibilities in high data rate wireless communications, security, night-vision, biomedical or video-imaging and gas sensing, detection technologies providing efficiency and sensitivity performances that can be “engineered” from scratch, remain elusive. Here, by exploiting the inherent electrical and thermal in-plane anisotropy of a flexible thin flake of black-phosphorus (BP), we devise plasma-wave, thermoelectric and bolometric nano-detectors with a selective, switchable and controllable operating mechanism. All devices operates at room-temperature and are integrated on-chip with planar nanoantennas, which provide remarkable efficiencies through light-harvesting in the strongly sub-wavelength device channel. The achieved selective detection (∼5–8 V/W responsivity) and sensitivity performances (signal-to-noise ratio of 500), are here exploited to demonstrate the first concrete application of a phosphorus-based active THz device, for pharmaceutical and quality control imaging of macroscopic samples, in real-time and in a realistic setting.