The unique urban form on the ground and the “city overlap city” phenomenon occurring underground at Kaifeng city, on the Yellow River floodplain, is investigated. Archaeological data and historical geographical analysis were used to study the form of surface remains. Primary data were collected from four 25 m long drill cores which were obtained from different locations at Kaifeng city and the sedimentary cycles were quantitatively divided-out and dated. The results show that the evolution of Kaifeng’s surface urban form mainly occurred over four periods, the first of which was before 225 BC; the second took place between 225 BC and 956 AD; the third between 956 AD and 1219 AD; and the fourth between 1219 AD and 1907 AD. The results support the view that the city wall of today has undergone continuous reconstruction on the basis of previous city walls and thus forming the special landscape sequence of overlapped walls as a result of the 1642 AD and 1841 AD floods. The results also substantiate the “city overlap city” phenomenon at Kaifeng city where there are at least “three and a half ancient cities” located underground today, and suggests the “city overlap city” landscape is a harmonious production comprising both natural and human heritages that are of worldwide significance in terms of authenticity and integrity. Our results contribute to understanding the effects of Yellow River flooding on shaping adaptive landscapes and human beings, and suggest that Kaifeng city as well as other lower Yellow River sites become World Heritage sites.
To explore the characteristics of PM2.5 and assess the health risks to residents in Shijiazhuang before and during the heating period in 2019, 2020 and 2021, the hourly concentrations of PM2.5 and its nine selected trace elements were determined. The results showed that the mass concentrations of PM2.5 were 80.32 ± 50.21 μg m−3 (2019), 69.97 ± 41.91 μg m−3 (2020) and 58.70 ± 41.97 μg m−3 (2021) during the heating period, representing greatly improved air quality. The PM2.5 levels in the heating period were 1.04~1.60 times greater than those before the heating period, while the total selected trace element concentrations were about 1.44~1.97 times higher, indicating that strict control for PM2.5 in the heating period should be imposed. The overall hazard quotient (HQ) of the nine selected trace elements in the heating period were 1.08~1.42 times higher than those before the heating period, while the total cancer risks (CR) were decreased by 29.04% (2020) and 3.50% (2021). There were high health risks not only in local areas, but also in the south of Hebei, the north of Henan, and southern and central Shanxi. The health risks increased by 1.21~2.26 times from clean levels to heavy pollution levels. The leading element of HQ was Mn, while the dominant elements of CR varied from As to Co. Increases in PM2.5 concentrations and HQ from before the heating period to during the heating period were observed, and there was even an inverse CR change between before the heating period and during the heating period, further identifying that air pollution control was efficient.
Fireworks burning (FB) constitutes a major but short-lived source of PM2.5 during the Chinese Spring Festival, significantly deteriorating air quality in certain regions. This study was conducted to evaluate its impact through real-time monitoring of PM2.5 chemical compositions in a forestry city (Xinyang) during the pre-fireworks and fireworks periods at the Spring Festival of 2023–2025. During the fireworks period, PM2.5 concentrations increased by 10.5–226.4% compared to pre-fireworks levels, of which the concentrations of secondary inorganic aerosols (SIA), K and Cl− rose by 1.6–4.8, 1.9–14.7 and 1.5–8.1 times, and they accounted for 33.2–47.7%, 6.7–12.5% and 3.8–6.4% of PM2.5, respectively. Correspondingly, PM2.5/CO and SIA/CO ratios in 2023–2025 elevated by factors of 1.4–2.3 and 1.1–3.4, indicating distinct enhancements in secondary inorganic aerosols formation. Additionally, acidity of PM2.5, RH and Ox also increased during fireworks. Collectively, higher sulfur and nitrogen oxidation ratios (SOR and NOR) during the fireworks period under the combined effects of high RH, Ox and acidity conditions indicated a greater conversion of secondary inorganic aerosols. Positive Matrix Factorization (PMF) analysis confirmed that FB and secondary aerosols (SA) source levels during fireworks increased by 2.5–19.3 and 1.9–4.4 times compared to pre-fireworks values. This study underscores the need for implementing stringent management of fireworks and secondary formation mitigation to reduce PM2.5 concentrations during the Spring Festival.