: A typical ground source heat pump (GSHP) system in South Korea has a ground heat exchanger (GHX) with a length of 100–150 m, which utilizes annually stable underground temperature to meet the loads of cooling, heating and hot water in buildings. However, most GSHP systems have been introduced in heating dominated areas because the system performance advantage is larger compared with air source heat pump system than that in cooling dominated areas. To effectively provide geothermal energy to the building in the limited urban area, it is necessary to install deep GHXs. Despite its large capacity, there are few studies on GSHP system with deep GHX over 300 m. In this study, to estimate the performance of the GSHP system with deep GHX and evaluate its feasibility, numerical simulation was conducted. To quantitatively analyze heat transfer between soil and GHX, the coupled model with GHX model and ground heat and groundwater transfer model was used. Furthermore, the heat exchange rate and the source temperature were calculated according to the operation modes, the length of GHX, and soil conditions such as geothermal gradient and thermal conductivity. As a result, the total heat exchange rate of GHX with a length of 300 m heat exchanger was 12.62 kW, 173% that of a length of 150 m. Finally, it was found that the GSHP system with deep GHX has realistic possibility in good condition of geothermal gradient.

The use of shallow geothermal energy systems utilizing groundwater temperature for the air-conditioning of buildings is increasing worldwide. The impact of these systems on groundwater quality has become crucial for environmental regulations and system design. For the long-term operation of geothermal systems, it is important to evaluate their influence on the geochemical properties of groundwater, including precipitation and dissolution of secondary minerals. This research was conducted in a real-scale geothermal system, consisting of a groundwater heat pump (GWHP). Hydrochemical data were obtained from samples collected from an aquifer before heating, during heating, and before cooling operations of the GWHP. The Langelier Saturation Index and Ryznar Stability Index were calculated, and the saturation index was simulated with the PHREEQC program. Evidence from water table variation, temperature change, and ${}^{87}$ Sr/ ${}^{86}$ Sr isotope distribution showed that groundwater flows from a well located on the northwest side of the geothermal well. The saturation index values showed that the pristine groundwater favors carbonate dissolution, however, manganese oxides are more sensitive to temperature than carbonate minerals. In addition, mineral precipitation and dissolution were found to vary with depth and temperature.

The water supply from headwater streams in mountainous regions is considered an important source for sustaining both water quality and quantity in lowland areas. The Korean terrain is characterized by mountainous regions, the hydrological environment is significantly impacted by seasonal weather conditions. This study focused on investigating the hydrochemistry and isotopic composition of groundwater and surface water to identify hydrological connectivity within a mountainous watershed area in Daejeon, Korea. The estimated recharge rate using water budget methods suggests that approximately 20% of the total precipitation contributes to groundwater recharge in this site. The δ¹⁸O–δ²H values of the water samples indicate a meteoric water source for groundwater recharge, while the isotope composition of surface water reveals altitude effects, implying that groundwater recharges at a higher altitude region. Additionally, water revealed altitude effects suggesting that the groundwater was inferred to recharge at a higher altitude region. The hydrochemical conservative components (⁸⁷Sr/⁸⁶Sr ratio and Cl⁻) indicate that this watershed undergoes temporary similar water–rock interactions along its flow path, but it is also impacted by anthropogenic contaminants from the surrounding public area. The results of the three-component endmember mixing analysis demonstrate that groundwater is predominantly influenced by surface water, indicating a close interrelationship among various water bodies in mountain hydrology. These findings provide a comprehensive approach to water resource management by combining recharge rate estimation and the assessment of water body connectivity using natural tracers.