This scientific paper provides an overview of the current state of pyrolysis in Europe, with a focus on mapping the key research areas and technologies employed. This research relied on search equations that centered on the utilization of biomass and plastics as primary feedstocks in pyrolysis, with a particular emphasis on biochar generation and different technologies applied. The results showed that both plastic and biomass pyrolysis can contribute to reducing waste and mitigating greenhouse gas emissions. However, plastic pyrolysis can release harmful pollutants due to the presence of chlorine and other additives in plastics, which requires sophisticated emission control systems to be implemented. The production of biochar from sewage sludge is identified as a promising approach for phosphorus recovery, which can subsequently be utilized as a valuable fertilizer in agricultural applications. The data from this study contribute to exploring future applications at pilot and industrial scales for pyrolysis, with a critical assessment of the use of feedstocks. Moreover, this work provides information about current companies that are already operating on a large scale with pyrolysis and a map of the principal countries in Europe engaged in pyrolysis research, correlating the characteristics of the pyrolysis processes investigated.

Coffee processing generates a large amount of organic waste, which has the potential for energy use through biogas production. Although Brazil dominates world coffee production, treating its residue with biogas technology is not a practice, especially due to this product’s seasonality, which hampers continuous digester operation. The implementation of biogas production from coffee residues in a concept of industrial symbiosis could overcome this. This work evaluates the biogas energy potential from the main liquid residues of coffee processing (i.e., mucilage and wash water) and their integration with glycerin and cattle manure. Around 2773 m³ biogas day⁻¹ would be produced (75% CH₄), used as biomethane (734 thousand m³ year⁻¹), or thermal energy (23,000,000 MJ year⁻¹), or electricity (2718 MWh year⁻¹), which could supply, respectively, all the liquefied petroleum gas (LPG) and diesel demands of the farm, all the thermal energy demands of the grain drying process, as well as electricity for 30 residences. Considering the short coffee season, the results have a broader context for the application of biogas production on coffee processing farms, envisaging that the Agroindustrial Eco-Park concept has the potential to integrate various agroindustrial sectors for energy production, residue exchange, and water recirculation.

Anaerobic digestion (AD) of residues from integrated first- and second-generation ethanol (1G2G) biorefineries is a sustainable method for energy recovery through biogas production. This study evaluated the co-digestion of 1G vinasse, 2G vinasse and pentose liquor (from the pretreatment of sugarcane bagasse for 2G ethanol production) compared to individual digestions using biochemical methane potential (BMP) assays. The results showed some “key” micronutrients from the substrates that affected methane (CH₄) production, while their balance provided by co-digestion achieved high digestibility (95%). High iron (Fe) and nickel (Ni) concentrations, in addition to furfural (0.33 g L⁻¹) in pentose liquor seemed to decrease its CH₄ production potential. Despite these adverse effects observed in mono-digestion, co-digestion was beneficial for this substrate, increasing digestibility (52%) and BMP (118%). The highest BMP was observed in vinasse 2G (631 ± 6 NmL CH₄ gTVS⁻¹), with no significant difference compared to the adjusted modified Gompertz model (624 ± 10 NmL CH₄ gTVS⁻¹). The co-digestion system also presented the highest specific CH₄ production rate (20 ± 1 NmL CH₄ gTVS⁻¹day⁻¹) and shortened the lag phase by 19% compared to the AD of isolated 1G vinasse with the second lowest BMP value (494 ± 11 NmL CH₄ gTVS⁻¹).