A combination of mechanical and chemical treatments was utilized to modify the surface textures of copper and duralumin inserts in order to enhance the adhesion at the metal–polymer interface and provide an adhesive joint with a high loadbearing capacity. Pretreatment of the surfaces with sandblasting was followed by etching with various chemical mixtures. The resulting surface textures were evaluated with a scanning electron microscope (SEM) and an optical confocal microscope. Surface geometry parameters (Sa, Sz, and Sdr) were measured and their relationships to the adhesion joint strength were studied. It was found that the virgin and purely mechanically treated inserts resulted in joints with poor loadbearing capacity, while a hundredfold (duralumin) and ninetyfold (copper) increase in the force to break was observed for some combinations of mechanical and chemical treatments. It was determined that the critical factor is overcoming a certain surface roughness threshold with the mechanical pretreatment to maximize the potential of the mechanical/chemical approach for the particular combination of material and etchant.
Polypropylene (PP) belongs among the most important commodity plastics due to its widespread application. The color of the PP products can be achieved by the addition of pigments, which can dramatically affect its material characteristics. To maintain product consistency (dimensional, mechanical, and optical), knowledge of these implications is of great importance. This study investigates the effect of transparent/opaque green masterbatches (MBs) and their concentration on the physico-mechanical and optical properties of PP produced by injection molding. The results showed that selected pigments had different nucleating abilities, affecting the dimensional stability and crystallinity of the product. The rheological properties of pigmented PP melts were affected as well. Mechanical testing showed that the presence of both pigments increased the tensile strength and Young’s modulus, while the elongation at break was significantly increased only for the opaque MB. The impact toughness of colored PP with both MBs remained similar to that of neat PP. The optical properties were well controlled by the dosing of MBs, and were further related to the RAL color standards, as demonstrated by CIE color space analysis. Finally, the selection of appropriate pigments for PP should be considered, especially in areas where dimensional and color stability, as well as product safety, are highly important.
This research investigates the micro-mechanical and tribological properties of injection-molded parts made from polypropylene. The tribological properties of polymers are a very interesting area of research. Understanding tribological processes is very crucial. Considering that the mechanical and tribological properties of injected parts are not uniform at various points of the part, this research was conducted to explain the non-homogeneity of properties along the flow path. Non-homogeneity can be influenced by numerous factors, including distance from the gate, mold and melt temperature, injection pressure, crystalline structure, cooling rate, the surface of the mold, and others. The key factor from the micro-mechanical and tribological properties point of view is the polymer morphology (degree of crystallinity and size of the skin and core layers). The morphology is influenced by polymer flow and the injection molding process conditions. Gained results indicate that the indentation method was sufficiently sensitive to capture the changes in polypropylene morphology, which is a key parameter for the resulting micro-mechanical and tribological properties of the part. It was proven that the mechanical and tribological properties are not equal in varying regions of the part. Due to cooling and process parameters, the difference in the indentation modulus in individual measurement points was up to 55%, and the tribological properties, in particular the friction coefficient, showed a difference of up to 20%. The aforementioned results indicate the impact this finding signifies for injection molding technology in technical practice. Tribological properties are a key property of the part surface and, together with micro-mechanical properties, characterize the resistance of the surface to mechanical failure of the plastic part when used in engineering applications. A suitable choice of gate location, finishing method of the cavity surface, and process parameters can ensure the improvement of mechanical and tribological properties in stressed regions of the part. This will increase the stiffness and wear resistance of the surface.
This study examines the process of using injection moulding to join two different materials to manufacture bi-component moulded products with improved performance characteristics. The two-component process, which combines the advantages of two different technologies—the high efficiency of the injection moulding process and the excellent mechanical properties of long glass fibre composites produced by resin transfer moulding (RTM) technology—offers a particular advantage and improved applicability of the prepared lightweight products in both the automotive and aerospace sectors. The composite studied here consists of Elium® thermoplastic resin (30%) reinforced with unwoven glass fibre fabric (70%) using the RTM process. The Elium® composite sample is consequently used as an insert overmoulded with polybutylene terephthalate (PBT) homopolymer reinforced with 20% w/w of short glass fibre through injection moulding. The influence of different mould temperatures and surface treatments on the adhesion between the materials used is investigated by evaluating the mechanical performance using tensile shear strength tests. It was found that while an increase in mould temperature from 40 °C to 120 °C resulted in a doubling of the initial average bond strength between untreated Elium® RTM inserts and overmoulded PBT parts (0.9 MPa), sandblasting the inserts ensured a further tripling of the bond strength of the composites to a value of 5.4 MPa.
This work is dedicated to the design of flexible composite elements, specifically leaf springs. The design of these flexible composite elements took in consideration the technologies, materials and intermediate goods that are available and useable in laboratory manufacturing and the possibility for the transfer of gained knowledge to industrial practice. This work deals with individual types of materials and their processability and usability for the manufacturing of composite products exposed to cyclic stress. The impact of the designed lay-up diagrams and cyclic load boundary on the fatigue behaviour of manufactured specimens was used to evaluate the effect of cyclic stressing. Based on this assessment, a conclusion and recommendation were formulated for the serial manufacturing of flexible composite elements.