The long convergence time and non-robust positioning accuracy are the main factors limiting the application of precision single-point positioning (PPP) in kinematic vehicle navigation. Therefore, a dual/triple-frequency multi-constellation PPP-RTK method with atmospheric augmentation is proposed to achieve cm-level reliable kinematic positioning. The performance was assessed using a set of static station and kinematic vehicle positioning experiments conducted in Wuhan. In the static experiments, instantaneous convergence within 1 s and centimeter-level positioning accuracy were achieved for PPP-RTK using dual-frequency observation. For the kinematic experiments, instantaneous convergence was also achieved for dual-frequency PPP-RTK in open areas, with RMS of 2.6 cm, 2.6 cm, and 7.5 cm in the north, east, and up directions, respectively, with accuracy similar to short-baseline real-time kinematic positioning (RTK). Horizontal positioning errors of less than 0.1 m and 3D positional errors of less than 0.2 m were 99.54% and 98.46%, respectively. Additionally, after the outage of GNSS and during satellite reduction in obstructed environments, faster reconvergence and greater accuracy stability were realized compared with PPP without atmospheric enhancement. Triple-frequency PPP-RTK was able to further enhance the robustness and accuracy of positioning, with RMS of 2.2 cm, 2.0 cm, and 7.3 cm, respectively. In summary, a performance similar to RTK was achieved based on dual-frequency PPP-RTK, demonstrating that PPP-RTK has the potential for lane-level navigation.