CdSe_xTe_1−x semiconductor nanocrystals (NCs), being rod-shaped/irregular dot-shaped in morphology, have been fabricated via a simple hot-injection method. The NCs composition is well controlled through varying molar ratios of Se to Te precursors. Through changing the composition of the CdSe_xTe_1−x NCs, the spectral absorption of the NC thin film between 570–800 nm is proved to be tunable. It is shown that the bandgap of homogeneously alloyed CdSe_xTe_1−x active thin film is nonlinearly correlated with the different compositions, which is perceived as optical bowing. The solar cell devices based on CdSe_xTe_1−x NCs with the structure of ITO/ZnO/CdSe/CdSe_xTe_1−x/MoO_x/Au and the graded bandgap ITO/ZnO/CdSe(w/o)/CdSe_xTe1−x/CdTe/MoO_x/Au are systematically evaluated. It was found that the performance of solar cells degrades almost linearly with the increase of alloy NC film thickness with respect to ITO/ZnO/CdSe/CdSe_0.2Te_0.8/MoO_x/Au. From another perspective, in terms of the graded bandgap structure of ITO/ZnO/CdSe/CdSe_xTe_1−x/CdTe/MoO_x/Au, the performance is improved in contrast with its single-junction analogues. The graded bandgap structure is proved to be efficient when absorbing spectrum and the solar cells fabricated under the structure of ITO/ZnO/CdSe_0.8Te_0.2/CdSe_0.2Te_0.8/CdTe/MoO_x/Au indicate power conversion efficiency (PCE) of 6.37%, a value among the highest for solution-processed inversely-structured CdSe_xTe_1−x NC solar cells. As the NC solar cells are solution-processed under environmental conditions, they are promising for fabricating solar cells at low cost, roll by roll and in large area.

PbS colloidal quantum dots (CQDs) solar cells have already demonstrated very impressive advances in recent years due to the development of many different techniques to tailor the interface morphology and compactness in PbS CQDs thin film. Here, n-hexane, n-octane, n-heptane, isooctane and toluene or their hybrids are for the first time introduced as solvent for comparison of the dispersion of PbS CQDs. PbS CQDs solar cells with the configuration of PbS/TiO₂ heterojunction are then fabricated by using different CQDs solution under ambient conditions. The performances of the PbS CQDs solar cells are found to be tuned by changing solvent and its content in the PbS CQDs solution. The best device could show a power conversion efficiency (PCE) of 7.64% under AM 1.5 G illumination at 100 mW cm⁻² in a n-octane/isooctane (95%/5% v/v) hybrid solvent scheme, which shows a ~15% improvement compared to the control devices. These results offer important insight into the solvent engineering of high-performance PbS CQDs solar cells.

We propose Sb-doped TiO₂ as electron acceptor material for depleted CdTe nanocrystal (NC) hetero-junction solar cells. Novel devices with the architecture of FTO/ZnO/Sb:TiO₂/CdTe/Au based on CdTe NC and TiO₂ precursor are fabricated by rational ambient solution process. By introducing TiO₂ with dopant concentration, we are able to tailor the optoelectronic properties of NC solar cells. Our novel devices demonstrate a very high open circuit voltage of 0.74 V, which is the highest V_oc reported for any CdTe NC based solar cells. The power conversion efficiency (PCE) of solar cells increases with the increase of Sb-doped content from 1% to 3%, then decreases almost linearly with further increase of Sb content due to the recombination effect. The champion device shows J_sc, V_oc, FF, and PCE of 14.65 mA/cm², 0.70 V, 34.44, and 3.53% respectively, which is prospective for solution processed NC solar cells with high V_oc.