Inorganic scintillation crystals have been widely used in applications of high-energy physics, nuclear medical imaging, industrial nondestructive inspection, etc. In this work, a single crystal Ba₃Y(PO₄)₃ (BYP) with 1.0 at% Ce³⁺-doping concentration was first grown by the Czochralski method, and the electronic structure was calculated using first principles based on density functional theory. In addition, a series of Ce³⁺-doped BYP phosphors were synthesized, and the fluorescence emission under UV excitation was measured through low-temperature spectroscopy, containing double-peaked emission from 5d–4f transition and self-trapped exciton recombination. A comparison of the UV and X-ray-excited fluorescence spectra reveals the existence of oxygen vacancies as well as F+ centers in the crystal. The air annealing of the crystal effectively reduces the thermoluminescence defects but reduces the emission intensity under UV or X-ray excitation. The BYP:Ce crystal shows a fast decay lifetime of 15.5 ns, and the fast component is as short as 8 ns. The results show that the Ce³⁺-doped BYP crystal has potential as a kind of scintillator with fast decay properties.

A disordered Nd:SrLaGaO₄ (Nd:SLG) laser crystal was successfully grown via the Czochralski (CZ) technique. The crystal structure, refractive index, polarized absorption spectra, and stimulated emission spectra were measured. The spectroscopic properties were studied intensively with the Judd–Ofelt (J-O) theory. The maximum absorption cross sections of π- and σ-polarization at 806 nm were calculated to be 3.73 × 10⁻²⁰ and 4.05 × 10⁻²⁰ cm², corresponding to FWHMs of 6.00 and 6.10 nm, respectively. The maximum emission cross sections of π- and σ-polarization at 1076 nm were 3.97 × 10⁻²⁰ and 4.12 × 10⁻²⁰ cm², with FWHMs of 30.21 and 19.44 nm, respectively. The decay life of the Nd³⁺:⁴F_3/2 energy level was fitted to be 0.152 ms, and the fluorescence quantum efficiency was 72.72%. The inhomogeneous broadening in spectra benefiting from the disordered structure indicates the Nd:SLG crystal is a promising gain medium for ultrafast laser and tunable laser generations in the near infrared region.

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