Two-dimensional (2D) materials are ultra-thin crystals with layered structures that have a monolayer and multiple layers of atomic thickness. Due to excellent performance, 2D materials represented by graphene have caused great interest from researchers in various fields, such as nano-electronics, sensors, solar cells, composite materials, and so on. In recent years, when graphite was used for liquid phase lubrication, there have been many disadvantages limiting its lubrication properties, such as stable dispersion, fluidity and so on. Therefore, 2D materials have been used as high-performance liquid-phase lubricant additives, which become a perfect entry point for high-performance nano-lubricants and lubrication applications. This review describes the application of 2D materials as additives in the field of liquid-phase lubrication (such as lubricating oil and water lubrication) in terms of experimental content, lubrication performance, and lubrication mechanism. Finally, the challenges and prospects of 2D materials in the lubrication field were also proposed.

Hydraulic fracturing is an important method of reservoir stimulation in the exploitation of geothermal resources, and conventional and unconventional oil and gas resources. In this article, hydraulic fracturing experiments with shale, sandstone cores (from southern Sichuan Basin), and granite cores (from Inner Mongolia) were conducted to investigate the different hydraulic fracture extension patterns in these three reservoir rocks. The different reactions between reservoir lithology and pump pressure can be reflected by the pump pressure monitoring curves of hydraulic fracture experiments. An X-ray computer tomography (CT) scanner was employed to obtain the spatial distribution of hydraulic fractures in fractured shale, sandstone, and granite cores. From the microscopic and macroscopic observation of hydraulic fractures, different extension patterns of the hydraulic fracture can be analyzed. In fractured sandstone, symmetrical hydraulic fracture morphology could be formed, while some micro cracks were also induced near the injection hole. Although the macroscopic cracks in fractured granite cores are barely observed by naked eye, the results of X-ray CT scanning obviously show the morphology of hydraulic fractures. It is indicated that the typical bedding planes well developed in shale formation play an important role in the propagation of hydraulic fractures in shale cores. The results also demonstrated that heterogeneity influenced the pathway of the hydraulic fracture in granite cores.

With the exploitation of shale gas booming all over the world, more and more studies are focused on the core technology, hydraulic fracturing, to improve commercial exploitation. Shale gas resources in China are enormous. In this research, a series of tests were carried out with samples of black organic-rich shale from the Lower Silurian Longmaxi formation, south China. Samples were drilled from different directions and were subjected to uniaxial and triaxial condition with various confining pressures, aiming at studying its rock mechanics properties, so as to provide basis for research and breakthrough of hydraulic fracturing technology. According to the results of the study, the development and distribution of shale’s bedding planes significantly impact its mechanical properties. Shale samples show obvious brittle characteristics under low confining pressure, and its mechanical behavior begins to transform from brittle to plastic characteristics with increasing confining pressure. Shale samples with different inclinations (β) have different sensitivities to the confining pressure. As a result, samples with 45° inclinations (β) are least sensitive. The strength of bedding planes is significantly lower than that of shale matrix, and tensile failure and shear failure generally tend to occur along the bedding planes. When hydraulic fracturing was conducted in shale formation with depth less than 2.25 km, corresponding to original in-situ of 60 MPa, cracks will preferably occur at first along the inclination (β) angle of 45° from the maximum principal stress, and the failure mode is most likely to be shear failure without volumetric strain. And, different modes of failure will occur at different locations in the reservoir, depending on the orientation of bedding inclined from the principle stress, which can probably explain the phenomenon why there are fractures along and cross the bedding planes during hydraulic fracturing treatment. When hydraulic fracturing was conducted in shale formation with depth greater than 2.25 km, hydraulic fractures may not crack along the bedding surfaces to some extent.