Global food trade expansion has enriched diets worldwide but also heightened concerns about contaminant spread. Per- and polyfluoroalkyl substances (PFAS) can persist in the environment for decades, yet their risks through food trade remain unclear. The global median estimated daily intake (EDI) of C8-PFAS (perfluorooctanoic acid and perfluorooctane sulfonate) (0.023 nanograms per kilograms per day) was mapped from 212 marine fish species, which indicated higher EDIs in North America, Oceania, and Europe. Furthermore, European countries play a pivotal role in C8-PFAS trade flows, markedly reshaping exposure pathways and driving increased exposure in many nations. These dynamics highlight the importance of establishing food-safety regulations and international trade standards. Although perfluorooctane sulfonate hazard index decreased by 72% after its 2009 regulations, unregulated long-chain PFAS continue to pose elevated risks.

This study provides guidance on using polyurethane foam-based passive air samplers (PUF-PASs) for atmospheric nonane chlorinated paraffins (C₉-CPs) and short-chain CPs (SCCPs) and reports SCCP concentrations in air in the Greater Toronto Area (GTA), Canada. We estimated the partition coefficients between PUF and air (K_PUF-A) and between octanol and air (K_OA) for C₉-CP and SCCP congeners using the COSMO-RS method, so that PUF disk uptake profiles for each formula group could be calculated. We then measured SCCP concentrations in PUF disk samples collected from distinct source sectors in urban air across the GTA. Concentrations in samplers were used to calculate C₉-CP and SCCP concentrations in air and the PUF disk uptake profiles revealed that time-weighted linear phase sampling was possible for congeners having log K_OA values greater than 8.5. The highest SCCP concentrations, with an annual average concentration of 35.3 ng/m³, were measured at the industrial site, whereas lower but comparable SCCP concentrations were found in residential and background sites, with annual averages of 7.73 and 10.5 ng/m³, respectively. No consistent seasonal variation in SCCP concentrations was found in the six distinct source sectors. Direct measurements of K_PUF-A and K_OA values as a function of temperature could be used to increase accuracy in future studies.