Due to its environmental and resource impacts, the geochemistry of uranium in coal is of both academic and practical significance. In order to give a comprehensive summary about the geochemistry of uranium in coals, the abundance, distribution, and modes of occurrence of uranium in Chinese coals were reviewed in this paper. Although some coals from southwestern and northwestern China are significantly enriched in uranium, the common Chinese coals are of a comparable uranium concentration to the world coals. The roof and floor rocks, and parting of coalbeds, or coal benches that are close to the surrounding rock are favorable hosts for uranium in one coalbed. The uranium concentrations in coals of different ages decrease in this order, e.g., Paleogene and Neogene > Late Permian > Late Triassic > Late Carboniferous and Early Permian > Late Jurassic and Early Cretaceous > Early and Middle Jurassic. Uranium in Chinese coals is mainly associated with organic matter, and is correspondingly enriched in subbituminous coal and lignite.

Uranium, which is of chemotoxic and radiotoxic, is connately present in coals. In view of its dual roles in resource recovery and environmental impact, the geochemistry of uranium in Chinese coals and its atmospheric emission by coal-fired plants in China are discussed in this article. The average uranium concentration of the majority of Chinese coals is 2.43 mg/kg, which is comparable to that of world coals. However, in coals from certain local regions of China, i.e. Yunnan, Guizhou, Guangxi, Xinjiang, Inner Mongolia, and Chongqing Provinces, the uranium is significantly enriched; and even abnormally enriched to form coal-hosted uranium deposits, e.g. coals from the Yili and Tarim Basins of Xinjiang Province, Bangmai Basin of Yunnan Province, and Mabugang Basin of Guangdong Province. Uranium in Chinese coals is associated with organic matter, silicates, pores, pelitic components, phosphate minerals, and uranium minerals. The enrichment of uranium in Chinese coals is attributed to the weathering of source rocks, volcanic ashes, magmatic intrusion, marine water influence, groundwater, hydrothermal fluids, organic matter, palaeoclimate, and the geologic conditions of coal-accumulating basins. Uranium is prior to partition into fly ash. About 62.9 tons of uranium were released into atmosphere from Chinese coal-fired power plants in 2014. Some environmental and human health problems were historically related to uranium in coal worldwide.