Developing materials for efficient energy storage and effective electromagnetic interference (EMI) shielding is crucial in modern technology. This study explores the synthesis and characterization of carbonaceous shape-stabilized octadecane/MWCNT (multi-walled carbon nanotube) composites, utilizing activated carbon, expanded graphite or ceramic carbon foam, as shape stabilizers for phase change materials (PCMs) to enhance thermal energy storage and EMI shielding, for energy-efficient and advanced applications. The integration of octadecane, a phase change material (PCM) with carbonaceous stabilizers ensures the material’s stability during phase transitions, while MWCNTs contribute to improved thermal storage properties and EMI shielding capabilities. The research aims to develop novel composites with dual functionality for thermal storage and EMI shielding, emphasizing the role of carbon matrices and their MWCNT composites. SEM and CT microtomography analyses reveal variations in MWCNT incorporation across the matrices, influenced by surface properties and porosity. Leaching tests, infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) confirm the composite’s stability and high latent heat storage. The presence of nanotubes enhances the thermal properties of octadecane and ΔH values almost reached their theoretical values. EMI shielding effectiveness measurements indicate that the composites show improved electric properties in the presence of MWCNTs.
Energy self-sufficiency, as well as optimal management of power in buildings is gaining importance, while obtaining power from traditional fossil energy sources is becoming more and more expensive. In this context, millimeter-scale metasurfaces can be employed to harvest energy from microwave sources. They can also be used as sensors in the microwave regime for efficient power management solutions. In the current study, a simple spray printing method is proposed to develop metasurfaces in construction materials, i.e., plasterboard and wood. Such materials are used in the interior design of buildings; therefore, the implementation of metasurfaces in large areas, such as walls, doors and floors, is realized. The fabricated metasurfaces were characterized regarding their electromagnetic performance. It is hereby shown that the investigated metasurfaces exhibit an efficient electromagnetic response in the frequency range (4–7 GHz), depending on the MS. Thus, spray-printed metasurfaces integrated on construction materials can potentially be used for electromagnetic applications, for buildings’ power self-efficiency and management.
In this study, elastomer composites, including silicone rubber and barium titanate, were fabricated by mechanical mixing, a low-cost, fast, and easy technique to produce highly dielectric materials. The resulting composites were investigated in terms of their dielectric and mechanical properties in terms of filler percentage in the mixture. Dielectric permittivity measurements were taken using the microwave regime, and uniaxial tensile tests were carried out for the study of the materials’ mechanical properties, while combined experiments were also carried out to investigate potential correlations between them. The experimental results show that barium titanate inclusions in silicone matrix significantly improve the dielectric constant while reducing the mechanical properties of composites. In addition, combined experiments show that the composites exhibit a nearly stable dielectric profile under mechanical deformations. Consequently, mechanically mixed barium titanate–silicone elastomer composites could potentially become a cost-effective alternative in the extensive market for insulating materials and flexible electronics.
In this study, a hybrid energy harvesting system based on a conventional solar cell combined with 3D-printed metasurface units is studied. Millimeter-scale metasurface units were fabricated via the stereolithography technique, and then they were covered with conductive silver paint, in order to achieve high electric conductivity. The performance of single, as well as two-unit metasurface harvesters, was thoroughly investigated. It was found that both of them produced voltage, which peaks at their resonance frequency, demonstrating efficient energy harvesting behavior in the microwave regime. Then, the metasurface units were connected with a commercially available photovoltaic panel and the performance of the hybrid system was examined under different environmental conditions, modifying the light intensity (i.e., light, dark and shadow). It was shown that the proposed hybrid harvesting system produces a sizable voltage output, which persists, even in the case when one of the components does not contribute. Furthermore, the performance of the hybrid harvester is found to be adequate enough, although optimization of the harvesting circuit is required in order to achieve high efficiency levels. All in all, the presented experimental evidence clearly indicates the realization of a rather promising hybrid energy harvesting system, exploiting two distinct ambient energy sources, namely light and microwaves.
In this study, millimeter-scale metasurfaces are examined concerning their capability as potential honey quality control sensors. In particular, complementary split-ring resonator metasurfaces were developed through the Computer Numerical Control engraving method. Under unloaded conditions, the metasurfaces exhibited fundamental resonance frequencies in the range of 3-6 GHz, depending on their size as well as the measurement orientation. Moreover, their electromagnetic response was studied in the presence of different honey types, such as chestnut, pine, and orange blossom honey. A corresponding resonance frequency shift was observed, suggesting the distinct electromagnetic response of the fabricated structures with respect to the honey type. Furthermore, the hereby studied resonators were tested against various types of honey adulteration, such as sweeteners (sugar and maple syrup), as well as microplastic contamination. The metasurfaces exhibit a discrete resonance frequency shift along with modulation of the resonance intensity in honey adulteration, enabling them to act as efficient honey quality detectors. In addition, their electromagnetic performance was compared to other state-of-the-art spectroscopic techniques dedicated to honey contamination, in particular, Raman and FTIR. It was found that spectroscopic evidence is consistent with the metasurface electromagnetic response, giving credence to their performance. All in all, it is evident that the hereby studied metasurfaces exhibit significant performance in honey adulteration sensing, allowing their potential application as sensors for honey quality control.