Consideration of the existence of hydrosilicate liquids (HSL) in nature can help in understanding the accumulation and transport of some mineral- and ore-forming components at the transition from magmas to hydrothermal fluids. We studied the experimental formation of HSL using a base system Na₂O-SiO₂-H₂O with addition of NaF, NaCl and metallic Ta. The interaction between quartz and aqueous solution, performed at 1.5 kbar and 600°C and followed either by cooling or by quench, showed that the formation of HSL occurred when initial Na₂O exceeded 2 wt %. Neither NaF nor NaCl have a significant effect on the formation of HSL. The HSL concentrates F, whereas Cl partitions into the aqueous fluid. With addition of Ta to the system, the HSL becomes metal-enriched. Natural analogs of experimental HSL can be found among “melt/fluid” inclusions entrapped in quartz and other minerals of miaroles in granite pegmatites and raremetal granites. The HSL is a novel medium enabling extreme concentrations of lithophile ore metals at the magmatic-hydrothermal transition.

The paper presents new geological, mineralogical, and isotope geochronological data for rare-metal pegmatites in the Kalba granitic batholith (Eastern Kazakhstan). Mineralization is especially abundant in the Central-Kalba ore district, where pegmatite bodies occur at the top of large granite plutons and at intersections of deep faults. The pegmatites contain several successive mineral assemblages from barren quartz-microcline and quartz-microcline-albite to Li-Cs-Ta-Nb-Be-Sn-bearing cleavelandite-lepidolite-spodumene. Ar-Ar muscovite and lepidolite ages bracket the metallogenic event between 291 and 286 Ma. The pegmatite mineral deposits formed synchronously with the emplacement of the phase 1 Kalba granites during the evolution of hydrous silicate rare-metal magmas that are produced by the differentiation of granite magma at large sources with possible inputs of F and rare metals with fluids.

Akutan Island hosts a volcano considered as one of most active in the Aleutian Arc. We build a new tomography model including the 3D distributions of the Vp, Vs, and Vp/Vs ratio based on arrival time data from more than 4,000 local earthquakes recorded by 13 seismic stations. In this model, we reveal a columnar anomaly of high Vp, low Vs, and high Vp/Vs ratio with a top boundary at a depth of ∼6 km below sea level, which represents a steady conduit feeding the Akutan volcano. In the upper part of the tomographic model, the highly heterogeneous structures are associated with interactions of shallow magmatic sources, meteoric and magmatic fluids, as well as degassing. Beneath the summit area of Akutan, we observe a prominent anomaly of high Vp/Vs, which may represent a shallow magma reservoir directly responsible for recent eruption activity and ongoing gas emission through the summit fumarole. The other fumarole field at the eastern flank of the volcano appears to be associated with a seismically active zone of low Vp/Vs ratio at depths of 2–4 km below surface. These structures indicate different depths of magma degassing in these two areas, which may explain distinct geochemical features of emitted gases. Besides the prominent anomaly representing the shallow magma reservoir beneath the caldera and the active cone, we observe several areas with high Vp/Vs ratio, some of which are interpreted as shallow magma storage regions, and some as zones of meteoric water penetration.

Atka is a subduction-related volcanic island located in the central part of Aleutian Arc. The northeastern part of this island forms the Atka Volcanic Complex (AVC), which is built as a relict shield volcano of a circular shape overlain by several active and extinct volcanic vents of different ages. During the past few decades, two active volcanoes within AVC—Korovin and Kliuchef—demonstrated mostly phreatic eruptions and intensive fumarolic activity. We have created the first tomographic model of the crust beneath AVC with the use of data of eight permanent stations of the Alaskan Volcanological Observatory operated in the time period from 2004 to 2017 that included arrival times of the P and S waves from local seismicity. Based on a series of checkerboard tests, we have demonstrated fair vertical and horizontal resolution of the model down to ~6 km depth. Beneath the Korovin and Kliuchef volcanoes, we have revealed two isolated anomalies of high Vp/Vs with values exceeding 2, which represent separate magma chambers that are responsible for magmatic eruptions of these two volcanoes. In shallow layers down to 2–3 km deep, we observe an alternation of zones with low and high values of the Vp/Vs ratio, which are likely associated with the circulation of meteoric fluids in the uppermost crust. Moderately high Vp/Vs anomalies indicate zones of meteoric water penetration down to the ground. On the other hand, the very low values of Vp/Vs reaching 1.5 depict the areas where meteoric water reached the hot magma reservoir and transformed into steam. On the surface, these zones coincide with the distributions of fumaroles. The outflow of these steam currents from active vents of Korovin and Kliuchef led to episodic phreatic eruptions, sometimes synchronous.

Experimental investigations in the system rare-metal granite–Na₂O–SiO₂–H₂O with the addition of aqueous solutions containing Rb, Cs, Sn, W, Mo, and Zn at 600°C and 1.5 kbar showed that the typical elements of rare-metal granites (Li, Rb, Cs, Be, Nb, and Ta) are preferentially concentrated in hydrosilicate liquids coexisting with aqueous fluid. The same behavior is characteristic of Zn and Sn, the minerals of which are usually formed under hydrothermal conditions. In contrast, Mo and W are weakly extracted by hydrosilicate liquids and almost equally distributed between them and aqueous fluids. Liquids similar to those described in this paper are formed during the final stages of magmatic crystallization in granite and granitepegmatite systems. The formation of hydrosilicate liquids in late magmatic and postmagmatic processes will be an important factor controlling the redistribution of metal components between residual magmatic melts, minerals, and aqueous fluids and, consequently, the mobility of these components in fluid-saturated magmatic systems enriched in rare metals.

The Badzhal tin magmatic-fluid system of the eponymous volcanoplutonic zone in the Middle Amur Region has been studied to reveal special characteristics of the transition from granite crystallization...