Solid oxide fuel cells (SOFCs) offer numerous advantages in terms of high efficiency and clean electrochemcial energy conversion devices. However, owing to high operation temperature, this technology is restricted to stationary applications and leads to components degradation and long-term stability issues. The development of new design and their modifications for improving the electrochemical performance at intermediate temperatures and durability of the SOFC components are very important to bring this technology one step closer to the market. In this context, the current research on the development, properties, performance, and stability of geometrically modified flat-tubular (FT) SOFC cell and the stack is reviewed in detail. This advanced design exhibits higher performance compared to the tubular type and longer stability in comparison to the planar type SOFCs. The application of the interconnect material is emerging as the key factor influencing the electrical output of the FT-SOFC and operation at high temperatures and current density are the critical issues for cell durability. New stack designs are discussed in detail and experimental findings are summarized.
19 June 2024 in Advances in Colloid and Interface Science
Hydrogen production through green methods is essential for achieving a green and sustainable energy goal. However, the slow reaction kinetics of the oxygen evolution reaction (OER) and the instability of catalysts for the hydrogen evolution reaction (HER) pose significant challenges to optimizing various water-splitting technologies. Herein, we present a comparative study encompassing mono- and binary metal–organic frameworks (MOFs) and mono- and binary ferrites, where ferrites outperform their MOF counterparts. Both binary MOFs and ferrites exhibited better performance than their mono variants. TEM analysis revealed the nanoscale morphology and crystalline features of the prepared ferrites. At the same time, EDS and BET analysis confirmed the chemical composition, specific surface area, and pore volume, highlighting their structural and electronic properties. Additionally, we compared piezo-photocatalysis and electrocatalysis, providing insights into the smart integration of both technologies. Gas chromatography demonstrated the synergistic coupling of piezoelectricity and photon-excited reactive species in Zn0.5Co0.5Fe2O4. Remarkably, the HER under both sonication and light achieved 484 μmol g−1 h−1, significantly higher than 232 μmol g−1 h−1 and 288 μmol g−1 h−1 for sonication and light alone, respectively. Electrochemical tests confirmed an OER and HER overpotential of 167 and 205 mV, respectively, along with 94% and 73% retention in chronoamperometry, validating its role as a multifunctional water-splitting electrolyzer. This work highlights the potential of designing innovative composites for stable and efficient water-splitting systems such as piezo-photocatalysis and electrocatalysis.
Schematic of the HBNG nanogenerator with a micro-pyramidal structure, illustrating layers of Kapton tape, Al foil, and PDMS-BaTiO3 composite. The micropyramidal design enhances contact sensitivity, boosting output voltages under mechanical stress.