Shumao Xu

Prof. Shumao Xu

Pennsylvania State University, State College, Pennsylvania, USA
+1
orcid

Research Focus & Metrics

Academic Career Length

12Years (2015-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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28 March 2019 in Angewandte Chemie International Edition
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Journal Article
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WRWenhao Ren
Wenhao Ren
XTXin Tan
Xin Tan
WYWanfeng Yang
Wanfeng Yang
CJChen Jia
Chen Jia
Shumao XuShumao Xu
Shumao Xu
CZChuan Zhao
Chuan Zhao

1 May 2020 in Matter
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Journal Article
Closed access
NZNannan Zhang
Nannan Zhang
FHFang Huang
Fang Huang
SZShenlong Zhao
Shenlong Zhao
XLXinghao Lv
Xinghao Lv
YZYihao Zhou
Yihao Zhou
XFXing Fan
Xing Fan

2 July 2021 in ACS Nano
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Journal Article
Closed access
ZZZhijie Zhang
Zhijie Zhang
Xiao XiaoXiao Xiao
Xiao Xiao
YZYihao Zhou
Yihao Zhou
LHLinjun Huang
Linjun Huang
YWYanxin Wang
Yanxin Wang
JCJun Chen
Jun Chen

10 October 2022 in Nature Communications
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XGXiaowei Guo
Xiaowei Guo
ESErhong Song
Erhong Song
WZWei Zhao
Wei Zhao
Shumao XuShumao Xu
Shumao Xu
WZWenli Zhao
Wenli Zhao
FHFuqiang Huang
Fuqiang Huang
Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS2 as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS2 (1T'''-MoS2) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS2 sample exhibits a low overpotential of 158 mV at 10 mA cm−2 and a Tafel slope of 74.5 mV dec−1 in acidic conditions, which are far exceeding the 2H-MoS2 counterpart (369 mV and 137 mV dec−1). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS2 with rich S vacancies.

1 June 2020 in Energy Storage Materials
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Guangtao ZanGuangtao Zan
Guangtao Zan
TWTong Wu
Tong Wu
PHPing Hu
Ping Hu
YZYihao Zhou
Yihao Zhou
SZShenlong Zhao
Shenlong Zhao
QWQingsheng Wu
Qingsheng Wu

20 December 2019 in Nature Communications
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Journal Article
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Shumao XuShumao Xu
Shumao Xu
XLXiao Liang
Xiao Liang
XWXue-Yan Wu
Xue-Yan Wu
SZShenlong Zhao
Shenlong Zhao
JCJun Chen
Jun Chen
JCJie-Sheng Chen
Jie-Sheng Chen
Inferior charge transport in insulating and bulk discharge products is one of the main factors resulting in poor cycling stability of lithium–oxygen batteries with high overpotential and large capacity decay. Here we report a two-step oxygen reduction approach by pre-depositing a potassium carbonate layer on the cathode surface in a potassium–oxygen battery to direct the growth of defective film-like discharge products in the successive cycling of lithium–oxygen batteries. The formation of defective film with improved charge transport and large contact area with a catalyst plays a critical role in the facile decomposition of discharge products and the sustained stability of the battery. Multistaged discharge constructing lithium peroxide-based heterostructure with band discontinuities and a relatively low lithium diffusion barrier may be responsible for the growth of defective film-like discharge products. This strategy offers a promising route for future development of cathode catalysts that can be used to extend the cycling life of lithium–oxygen batteries.