The reaction of water with Al-based alloys presents a promising alternative for on-board hydrogen production. This method, free from carbon emissions, has the advantage of addressing issues related to hydrogen storage and logistics. Al-Sn-Fe alloys are potential candidates for this application. However, the current literature lacks an in-depth understanding of the role of microstructural evolution in the hydrogen generation performance of these alloys. The present work investigates the influence of the microstructural length scale on the hydrogen production behavior of an Al-9Sn-1Fe (wt.) alloy. Directionally solidified samples with different microstructural length scales were subjected to hydrogen evolution tests in a 1 M NaOH solution. The results revealed that the microstructure of the studied alloy comprised α-Al-phase dendrites with a plate-like morphology along with the presence of Sn-rich particles and Al₁₃Fe₄ intermetallic compounds (IMCs) in the interdendritic areas. In addition, the microstructural refinement induced a 56.25% rise in hydrogen production rate, increasing from 0.16 to 0.25 mL g^–1 s^–1, without affecting the hydrogen yield, which stayed around 88%. The corrosion process was observed to be stimulated by Sn-rich particles and Al₁₃Fe₄ IMCs at their interfaces with the α-Al phase, positively impacting the hydrogen production rate. An experimental equation based on the Hall–Petch relationship and multiple linear regression (MLR) is proposed to associate the hydrogen production rate with dendritic arm spacings.

Monotectic alloys are of great industrial importance because of their favorable tribological behavior. Many studies in order to better understand the morphologies obtained by monotectic reaction have been developed. To better understand the morphologies obtained by monotectic Al-1.2wt%Pb alloy reaction, especially in relation to induced convective flow, this paper aims to compare the microstructural evolution of the alloy obteind by directional solidification in transient heat-flow conditions in upward, downwand and horizontal solidification devices. It was observed a morphology transition from particles to fibers on upward and downward cases and a morphology of only particles on the horizontal case. The classical relationship used for eutectic growth, λ²v = C, which was considered applicable to monotectic reactions, didn’t seemed to be valid in the interphase spacing evolution for the downward device, however power functions (λ = C.v^a) were found in all cases.

This study investigates the influence of quenching and partitioning (Q&P) on the microstructure, hardness, wear resistance, and impact toughness of GG25 gray cast iron, in comparison with as-cast, quenched, quenched-and-tempered, and austempered conditions. Q&P treatment promotes a significant fraction of retained austenite, with carbon enrichment stabilizing the austenite at room temperature. Microstructural analysis reveals a multiphase matrix composed of partitioned martensite, bainitic ferrite and carbon-enriched retained austenite, while the morphology and distribution of graphite flakes remain unchanged. Mechanical testing shows that Q&P enhances impact toughness without substantial loss of hardness, achieving a balance not observed in conventional quenching and tempering treatments. Tribological evaluation indicates that wear resistance is slightly lower than quenched and tempered samples but superior to as-cast iron, with deformation of retained austenite and tribofilm formation influencing wear behavior. These results demonstrate that Q&P represents a promising route for developing gray cast irons with enhanced toughness and maintained hardness, suitable for components subjected to impact and wear loading.