Well-documented outcrops around the Emeishan Large Igneous Province (ELIP) in South China, eastern Tethys, encompassing the end-Guadalupian mass extinction have been investigated. Correlatable sections recording the event exhibit very similar lithological characters, positive-then-negative C isotope excursions and massive biotic demise. Detailed analyses of the fossil record and carbon isotopic variations were carried out on the Guadalupian–Wuchiapingian Boundary sections over the inner, middle, outer zones of the ELIP and its margin. Due to a pronounced decrease in marine habitat area and the environmental and ecological change over this part of the Tethys, the biota crisis records show the loss of numerous tropical invertebrate taxa, and exhibit fewer genera and smaller testing sizes and low productivity. The biota crisis was a sustainable and gradual reduction in diversity over the Capitanian. The associated carbon isotopic data reveal unusually high δ13C(carb) values before the late Capitanian, representing higher primary productivity (or buried rate) and more 13C-enriched CO2 released by hydrothermal carbonate breakdown from the upper crust into the sediments at that time. Subsequently, an accelerated negative excursion across the boundary and the gradual excursion with low carbon isotope amplitude favours an increased influx of light 12C sourced by the volcanism around the eastern Tethys. The very similar time–space relation between the biota crisis and the Emeishan volcanism confirms that volcanic eruptions may have triggered the biota crisis event in South China. Intensive volcanism could result in detrimental environmental and ecological stresses, habitat loss, organic material splitting, or the emission of light carbon and thermal fluid (or aerosol), implying that the losses of the shallow-marine invertebrates either occurred geologically instantaneously or in a series of closely spaced crises coinciding with the initial phase of ELIP formation. These findings in South China may reveal the causal relation between mass extinctions and LIPs in a global context.
The Permian Longtan Formation in the Songzao coalfield, Southwest China, has abundant coalbed methane (CBM) stored in high-rank coals. However, few studies have been performed on the mechanism underlying the differences in CBM gas content in high-rank coal. This study focuses on the characterization of coal geochemical, reservoir physical, and gas-bearing properties in the coal seams M6, M7, M8, and M12 based on the CBM wells and coal exploration boreholes, discusses the effects of depositional environment, tectono-thermal evolution, and regional geological structure associated with CBM, and identifies major geological constraints on the gas-bearing properties in high-rank coal. The results show that high-rank coals are characterized by high TOC contents (31.49~51.32 wt%), high Tmax and R0 values (averaging 539 °C and 2.17%), low HI values (averaging 15.21 mg of HC/g TOC), high porosity and low permeability, and high gas-bearing contents, indicating a post-thermal maturity and a good CBM production potential. Changes in the shallow bay–tidal flat–lagoon environment triggered coal formation and provided the material basis for CBM generation. Multistage tectono-thermal evolution caused by the Emeishan mantle plume activity guaranteed the temperature and time for overmaturation and thermal metamorphism and added massive pyrolytic CBM, which improved the gas production potential. Good geological structural conditions, like enclosed fold regions, were shown to directly control CBM accumulation.