Supercritical carbon dioxide (SCO₂) is widely used in many fields of energy and power engineering, such as nuclear reactors, solar thermal power generation systems, and refrigeration systems. In practical applications, SCO₂ undergoes a cooling process significantly when it is cooled near the pseudo–critical point. Because of the drastic variations in thermo–physical properties, the heat transfer characteristics fluctuate, affecting the heat exchange and overall cycle performance. This paper summarizes extensive experiments and numerical simulations on the cooling process of SCO₂ in various application scenarios. The effects of various working conditions, such as mass flow, working pressure, pipe diameter, flow direction, and channel shapes, are reviewed. The applicability and computational results using different numerical methods under different working conditions are also summarized. Furthermore, empirical correlations obtained in experiments at different conditions are included. The present review can provide a helpful guideline for the design of effective cooling systems or condensers so that the accuracy of the design and efficiency of the system can be improved.

With the recognition of the multiple advantages of sulfonated hydrocarbon-based polymers that possess high chemical and mechanical stability with significant low cost, we employed molecular dynamics simulation to explore the morphological effects of side chain length in sulfonated polystyrene grafted poly(arylene ether sulfone)s (SPAES) proton exchange membranes. The calculated diffusion coefficients of hydronium ions (H₃O⁺) are in range of 0.61–1.15 × 10⁻⁷ cm²/s, smaller than that of water molecules, due to the electrical attraction between the oppositely charged sulfonate group and H₃O⁺. The investigation into the radial distribution functions suggests that phase segregation in the SPAES membrane is more probable with longer side chains. As the hydration level of the membranes in this study is relatively low (λ = 3), longer side chains correspond to more water molecules in the amorphous cell, which provides better solvent effects for the distribution of sulfonated side chains. The coordination number of water molecules and hydronium ions around the sulfonate group increases from 1.67 to 2.40 and from 2.45 to 5.66, respectively, with the increase in the side chain length. A significant proportion of the hydronium ions appear to be in bridging configurations coordinated by multiple sulfonate groups. The microscopic conformation of the SPAES membrane is basically unaffected by temperature during the evaluated temperature range. Thus, it can be revealed that the side chain length plays a key role in the configuration of the polymer chain and would contribute to the formation of the microphase separation morphology, which profits proton transport in the hydrophilic domains.