In this work, the concept of plasma–metal junction (pm-junction) is presented, in addition to well established physics of pn-junction, metal–semiconductor junction, semiconductor–insulator junction, etc. We demonstrate experimentally the dependence of I-V characteristics on work function of the metal for a pm-junction. The experiment is done using tungsten (W) and stainless steel (SS) having different work functions (${\Phi }_m$ ) of 4.55 eV and 4.30 eV, respectively. The W and SS planar metal probes of identical geometry were exposed to plasma simultaneously, making two distinct pm-junctions. The plasma exposed is identical for both the metals, and therefore, the difference observed in the I-V characteristics of these two pm-junctions is attributed only to the difference in an energy-band diagram of these junctions, owing to respective work function. The proposed concept of the pm-junction may simplify the complex plasma–material interactions in all laboratory plasmas, including cold glow discharges to hot fusion plasmas.

In a typical nitrogen glow discharge plasma, a large number of energetic neutrals, N ₂ , are generated inside the cathode sheath. In this work, we are presenting a technique for the extraction of this energetic N ₂ for the treatment of starch. The energetic neutrals N ₂ were generated by the application of −500 V on a transparent cathode. On reaching the cathode, N ₂ ⁺ ions are absorbed; however, it is transparent to energetic N ₂ neutrals molecules generated inside the sheath by charge exchange collisions, as the energetic N ₂ neutrals are unaffected by the electric field and pass through the transparent cathode. The sample for treatment was placed below the transparent cathode and thus exposed to the energetic N ₂ neutrals extracted from glow discharge plasma for a duration of 30 min. The impact of energetic N ₂ neutral extracted from glow discharge plasma results in modification of physical and thermal properties of corn starch (maize starch). The physicochemical and morphological properties of treated and untreated samples were studied. The surface roughness of the plasma-treated corn starch increased significantly in comparison to the untreated sample. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) spectra confirmed that there is a considerable reduction in the semicrystalline nature and the polymer structure morphology of the corn starch. Scanning electron microscope (SEM) micrographs of samples show a substantial change in surface morphology and in size of the grains between the plasma-treated and untreated corn starch samples. The room-temperature thermal properties of the plasma-treated corn starch samples are measured using differential scanning calorimetry (DSC). The results confirm that the starch treated with energetic N ₂ molecules has a lower gelatinization temperature and could be applied in food processing industries.

The organic adduct compounds of 2-nitrobenzoic acid crystals were grown as optically transparent crystals using the conventional slow evaporation solution technique. The crystals were powdered and irradiated with cold plasma. Cell parameter analysis confirmed the formation of a new crystalline material that resides in the triclinic P crystal system with space group P1. Fourier transform infrared spectra were recorded using the KBr pellet technique to determine the vibrational functional groups in the compound. Powder X-ray diffraction analysis was used to reveal the crystalline orientation of the powdered samples of the grown crystals. The obtained full width at half maximum for the (001) plane in the XRD spectrum indicates the excellent crystalline quality of the 2-nitrobenzoic acid crystals. The recorded UV–Vis absorption spectra reveal that the grown powdered crystal samples possess cut-off edges wavelengths at 428 and 428 nm and 353 and 354 nm for pure and plasma-treated samples, respectively. The optical energy bandgaps were found to be 2.0, 2.25, 4.06, and 4.02 eV for the pure and plasma-treated samples, respectively. The photoluminescence spectra show the blue emissions of the crystal. The FE-SEM images show the morphological modifications in which rounded platelets appear on the surfaces of the treated crystals.