While β-diketiminate (BDI or ‘nacnac’) ligands have been widely adopted to stabilize a wide range of metal ions in multiple oxidation states and coordination numbers, in several occurrences these ligands do not behave as spectators and participate in reactivity.
4 November 2012 in Angewandte Chemie International Edition
New tris-amidinate actinide (Th, U) complexes containing a rare O-bound terminal phosphaethynolate (OCP−) ligand were synthesized and fully characterized.
29 October 2019 in Journal of the American Chemical Society