Groundwater origin, flow and geochemical evolution in the Golmud River watershed of the Qaidam Basin was assessed using hydrogeochemical, isotopic and numerical approaches. The stable isotopic results show groundwater in the basin originates from precipitation and meltwater in the mountainous areas of the Tibetan Plateau. Modern water was found in the alluvial fan and shallow aquifers of the loess plain. Deep confined groundwater was recharged by paleowater during the late Pleistocene and Holocene under a cold climate. Groundwater in the low-lying depression of the central basin is composed of paleobrines migrated from the western part of the basin due to tectonic uplift in the geological past. Groundwater chemistry is controlled by mineral dissolution (halite, gypsum, anhydrite, mirabilite), silicate weathering, cation exchange, evaporation and mineral precipitation (halite, gypsum, anhydrite, aragonite, calcite, dolomite) and varies from fresh to brine with the water types evolving from HCO₃ ⋅ Cl-Ca ⋅ Mg ⋅ Na to Cl-Na, Cl-K-Na and Cl-Mg type along the flow path. Groundwater flow patterns are closely related to stratigraphic control and lithological distribution. Three hierarchical groundwater flow systems, namely local, intermediate and regional, were identified using numerical modeling. The quantity of water discharge from these three systems accounts for approximately 83 %, 14 % and 3 %, respectively, of the total groundwater quantity of the watershed. This study can enhance the understanding of groundwater origin, circulation and evolution in the Qaidam Basin as well as other arid endorheic watersheds in northwestern China and elsewhere worldwide.

Based on the geo-statistical theory and ArcGIS geo-statistical module, datas of 30 groundwater level observation wells were used to estimate the decline of groundwater level in Beijing piedmont. Seven different interpolation methods (inverse distance weighted interpolation, global polynomial interpolation, local polynomial interpolation, tension spline interpolation, ordinary Kriging interpolation, simple Kriging interpolation and universal Kriging interpolation) were used for interpolating groundwater level between 2001 and 2013. Cross-validation, absolute error and coefficient of determination (R2) was applied to evaluate the accuracy of different methods. The result shows that simple Kriging method gave the best fit. The analysis of spatial and temporal variability suggest that the nugget effects from 2001 to 2013 were increasing, which means the spatial correlation weakened gradually under the influence of human activities. The spatial variability in the middle areas of the alluvial–proluvial fan is relatively higher than area in top and bottom. Since the changes of the land use, groundwater level also has a temporal variation, the average decline rate of groundwater level between 2007 and 2013 increases compared with 2001–2006. Urban development and population growth cause over-exploitation of residential and industrial areas. The decline rate of the groundwater level in residential, industrial and river areas is relatively high, while the decreasing of farmland area and development of water-saving irrigation reduce the quantity of water using by agriculture and decline rate of groundwater level in agricultural area is not significant.

The usage of reclaimed water can efficiently mitigate water crises, but it may cause groundwater pollution. To clearly understand the potential influences of long-term reclaimed water usage, a total of 91 samples of shallow and deep groundwater were collected from a typical reclaimed water use area during the dry and rainy seasons. The results suggest both shallow and deep groundwater are mainly naturally alkaline freshwater, which are composed mainly of Ca-HCO₃, followed by mixed types such as Ca-Na-HCO₃ and Ca-Mg-HCO₃. A seasonal desalination trend was observed in both shallow and deep aquifers due to dilution effects in the rainy season. Groundwater chemical compositions in both shallow and deep aquifers are still dominantly controlled by natural processes such as silicate weathering, minerals dissolution and cation exchange. Human activities are also the factors influencing groundwater chemistry. Urbanization has been found responsible for the deterioration of groundwater quality, especially in shallow aquifers, because of the relative thin aquitard. Reclaimed water usage for agricultural irrigation and landscape purposes has nearly no influences on groundwater quality in rural areas due to thick aquitards. Therefore, reclaimed water usage should be encouraged in arid and semiarid areas with proper hydrogeological condition.

In this study, a mathematical expression describing the relationship between infiltration rate and soil moisture content was deduced based on the Horton equation in order to study the relationship between infiltration rate and soil moisture content during the rainfall infiltration process. Specific experimental data on infiltration processes were used to verify the validity of the equations and to analyze the main factors affecting the infiltration rate. The results indicate the following: (1) The experimental data demonstrated a high degree of accuracy. The volumetric error of soil moisture increase and cumulative infiltration was 3.5% and the coefficient of determination (R²) was 0.87 in the 42 tests. (2) The equation obtained in this paper can well describe the relationship between infiltration rate and soil moisture content; the R² of the fitted results was greater than 0.80 in more than 80% of the experiments. (3) The relationship between infiltration rate and soil moisture content is mainly influenced by initial soil moisture content; the higher the initial soil moisture content, the lower the initial infiltration rate, the faster the infiltration rate decreases with soil moisture content, and the lower the “relative stable infiltration rate” in the process of infiltration.