International audienceIn their late stages of evolution, peraluminous granitic melts exsolve large amounts of fluidswhich can modify the chemical composition of granitic whole-rock samples. The niobium/tantalum (Nb/Ta) ratio is expected to decrease during the magmatic differentiation of graniticmelts, but the behavior of both elements at the magmatic-hydrothermal transition remainsunclear. Using a compilation of whole-rock geochemical data available in the literature, wedemonstrate that fractional crystallization alone is not sufficient to explain the distribution ofNb-Ta in most peraluminous granites. However, we notice that most of the granitic samplesdisplaying evidence of interactions with fluids have Nb/Ta < 5. We propose that the decreaseof the Nb/Ta ratio in evolved melts is the consequence of both fractional crystallization andsub-solidus hydrothermal alteration. We suggest that the Nb/Ta value of ~5 fingerprints themagmatic-hydrothermal transition in peraluminous granites. Furthermore, a Nb/Ta ratio of ~5appears to be a good marker to discriminate mineralized from barren peraluminous granites

Much of the present-day volume of Earth’s continental crust had formed by the end of the Archean Eon, 2.5 billion years ago, through the conversion of basaltic (mafic) crust into sodic granite of tonalite, trondhjemite and granodiorite (TTG) composition. Distinctive chemical signatures in a small proportion of these rocks, the so-called high-pressure TTG, are interpreted to indicate partial melting of hydrated crust at pressures above 1.5 GPa (>50 km depth), pressures typically not reached in post-Archean continental crust. These interpretations significantly influence views on early crustal evolution and the onset of plate tectonics. Here we show that high-pressure TTG did not form through melting of crust, but through fractionation of melts derived from metasomatically enriched lithospheric mantle. Although the remaining, and dominant, group of Archean TTG did form through melting of hydrated mafic crust, there is no evidence that this occurred at depths significantly greater than the ~40 km average thickness of modern continental crust.

An increasing number of field examples in mountain belts show that the formation of passive margins during extreme continent thinning may occur under conditions of high to very high thermal gradient beneath a thin cover of syn-rift sediments. Orogenic belts resulting from the tectonic inversion of distal margins and regions of exhumed continental mantle may exhibit high-temperature, low-pressure (HT-LP) metamorphism and coeval syn-extensional, ductile deformation. Recent studies have shown that the northern flank of the Pyrenean belt, especially the North Pyrenean Zone, is one of the best examples of such inverted hot, passive margin. In this study, we provide a map of HT-LP metamorphism based on a data set of more than 100 peak-temperature estimates obtained using Raman spectroscopy of the carbonaceous material (RSCM). This data set is completed by previous PT (pressure and temperature) estimates based on mineral assemblages, and new 40Ar–39Ar (amphibole, micas) and U–Pb (titanite) ages from metamorphic and magmatic rocks of the North Pyrenean Zone. The implications on the geological evolution of the Cretaceous Pyrenean paleomargins are discussed. Ages range mainly from 110 to 90 Ma, and no westward or eastward propagation of the metamorphism and magmatism can be clearly identified. In contrast, the new data reveal a progressive propagation of the thermal anomaly from the base to the surface of the continental crust. Focusing on the key localities of the Mauléon basin, Arguenos–Moncaup, Lherz, Boucheville and the Bas-Agly, we analyze the thermal conditions prevailing during the Cretaceous crustal thinning. The results are synthetized into a series of three regional thematic maps and into two detailed maps of the Arguenos–Moncaup and Lherz areas. The results indicate a first-order control of the thermal gradient by the intensity of crustal thinning. The highest grades of metamorphism are intimately associated with the areas where subcontinental mantle rocks have been unroofed or exhumed.