Due to its high short-term global warming potential (GWP) compared to carbon dioxide, methane (CH₄) is a considerable agent of climate change. This research is aimed at analyzing data on methane gathered at the GAW (Global Atmosphere Watch) station of Lamezia Terme (Calabria, Southern Italy) spanning seven years of continuous measurements (2016–2022) and integrating the results with key meteorological data. Compared to previous studies on detected methane mole fractions at the same station, daily-to-yearly patterns have become more prominent thanks to the analysis of a much larger dataset. Overall, the yearly increase of methane at the Lamezia Terme station is in general agreement with global measurements by NOAA, though local peaks are present, and an increase linked to COVID-19 is identified. Seasonal changes and trends have proved to be fully cyclic, with the daily cycles being largely driven by local wind circulation patterns and synoptic features. Outbreak events have been statistically evaluated depending on their weekday of occurrence to test possible correlations with anthropogenic activities. A cross analysis between methane peaks and specific wind directions has also proved that local sources may be deemed responsible for the highest mole fractions.

In Southern Mediterranean regions, the issue of summer fires related to agriculture practices is a periodic recurrence. It implies a significant increase in carbon dioxide (CO₂) emissions and other combustion-related gaseous and particles compounds emitted into the atmosphere with potential impacts on air quality and global climate. In this work, we performed an analysis of summer fire events that occurred on August 2021. Measurements were carried out at the permanent World Meteorological Organization (WMO)/Global Atmosphere Watch (GAW) station of Lamezia Terme (Code: LMT) in Calabria, Southern Italy. The observatory is equipped with greenhouse gases and black carbon analyzers, an atmospheric particulate impactor system, and a meteo-station for atmospheric parameters to characterize atmospheric mechanisms and transport for land and sea breezes occurrences. High mole fractions of carbon monoxide (CO) and carbon dioxide (CO₂) coming from quadrants of inland areas were correlated with fire counts detected via the MODIS satellite (GFED-Global Fire Emissions Database) at 1 km of spatial resolution. In comparison with the typical summer values, higher CO and CO₂ were observed in August 2021. Furthermore, the growth in CO concentration values in the tropospheric column was also highlighted by the analyses of the L2 products of the Copernicus SP5 satellite. Wind fields were reconstructed via a Weather Research and Forecasting (WRF) output, the latter suggesting a possible contribution from open fire events observed at the inland region near the observatory. So far, there have been no documented estimates of the effect of prescribed burning on carbon emissions in this region. This study suggested that data collected at the LMT station can be useful in recognizing and consequently quantifying emission sources related to open fires.

The key to a sustainable future is the reduction in humankind’s impact on natural systems via the development of new technologies and the improvement in source apportionment. Although days, years and seasons are arbitrarily set, their mechanisms are based on natural cycles driven by Earth’s orbital periods. This is not the case for weeks, which are a pure anthropic category and are known from the literature to influence emission cycles and atmospheric chemistry. For the first time since it started data gathering operations, CO (carbon monoxide), CO₂ (carbon dioxide), CH₄ (methane) and eBC (equivalent black carbon) values detected by the Lamezia Terme WMO/GAW station in Calabria, Southern Italy, have been evaluated via a two-pronged approach accounting for weekly variations in absolute concentrations, as well as the number of hourly averages exceeding select thresholds. The analyses were performed on seven continuous years of measurements from 2016 to 2022. The results demonstrate that the analyzed GHGs (greenhouse gasses) and aerosols respond differently to weekly cycles throughout the seasons, and these findings provide completely new insights into source apportionment characterization. Moreover, the results have been combined into a new parameter: the hereby defined WDWO (Weighed Distribution of Weekly Outbreaks) normalizes weekly trends in CO, CO₂, CH₄ and eBC on an absolute scale, with the scope of providing regulators and researchers alike with a new tool meant to better evaluate anthropogenic pollution and mitigate its effects on the environment and human health.

Unlike stratospheric ozone (O₃), which is beneficial for Earth due to its capacity to screen the surface from solar ultraviolet radiation, tropospheric ozone poses a number of health and environmental issues. It has multiple effects that drive anthropogenic climate change, ranging from pure radiative forcing to a reduction of carbon sequestration potential in plants. In the central Mediterranean, which itself represents a hotspot for climate studies, multi-year data on surface ozone were analyzed at the Lamezia Terme (LMT) WMO/GAW coastal observation site, located in Calabria, Southern Italy. The site is characterized by a local wind circulation pattern that results in a clear differentiation between Western-seaside winds, which are normally depleted in pollutants and GHGs, and Northeastern-continental winds, which are enriched in these compounds. This study is the first detailed attempt at evaluating ozone concentrations at LMT and their correlations with meteorological parameters, providing new insights into the source of locally observed tropospheric ozone mole fractions. This research shows that surface ozone daily and seasonal patterns at LMT are “reversed” compared to the patterns observed by comparable studies applied to other parameters and compounds, thus confirming the general complexity of anthropogenic emissions into the atmosphere and their numerous effects on atmospheric chemistry. These observations could contribute to the monitoring and verification of new regulations and policies on environmental protection, cultural heritage preservation, and the mitigation of human health hazards in Calabria.

In 2020, the COVID-19 outbreak led many countries across the globe to introduce lockdowns (LDs) that effectively caused most anthropic activities to either stop completely or be significantly reduced. In Europe, Italy played a pioneeristic role via the early introduction of a strict nationwide LD on March 9th. This study was aimed at evaluating, using both chemical and meteorological data, the environmental response to that occurrence as observed by the Lamezia Terme (LMT) GAW/WMO station in Calabria, Southern Italy. The first 2020 lockdown was therefore used as a “proving ground” to assess CO, CO₂, CH₄, BC, and NO_x concentrations in a rather unique context by exploiting the location of LMT in the context of the Mediterranean Basin. In fact, its location on the Tyrrhenian coast of Calabria and local wind circulation both lead to daily cycles where western-seaside winds depleted in anthropogenic pollutants can be easily differentiated from northeastern-continental winds, enriched in anthropogenic outputs. In addition to this, the first Italian LD occurred during the seasonal transition from winter to spring and, consequently, summer, thus providing new insights on emission outputs correlated with seasons. The findings clearly indicated BC and, in particular, CO as strongly correlated with average daily temperatures, as well as possibly domestic heating. CO₂’s reduction during the lockdown and consequent increase in the post-lockdown period, combined with wind data, allowed us to constrain the local source of emissions located northeast from LMT. NO_x reductions during specific circumstances were consistent with hypotheses from previous research, which linked them to rush hour traffic and other forms of transportation emissions. CH₄’s stable patterns were consistent with livestock, landfills, and other sources assumed to be nearly constant during LD periods.

Due to its high short-term global warming potential (GWP) compared to carbon dioxide, methane (CH₄) is a considerable agent of climate change. This research is aimed at analyzing data on methane gathered at the GAW (Global Atmosphere Watch) station of Lamezia Terme (Calabria, Southern Italy) spanning seven years of continuous measurements (2016-2022) and integrating the results with key meteorological data. Compared to previous studies on detected methane mole fractions at the same station, daily-to-yearly patterns have become more prominent thanks to the analysis of a much larger data set. Overall, the yearly increase of methane at the Lamezia Terme station is in general agreement with global measurements by NOAA, though local peaks are present, and an increase linked to Covid-19 is identified. Seasonal changes and trends have proved to be fully cyclic, with the daily cycles being largely driven by local wind circulation patterns and synoptic features. Outbreak events have been statistically evaluated depending on their weekday of occurrence to test possible correlations with anthropic activities. A cross analysis between methane peaks and specific wind directions has also proved that local sources may be deemed responsible for the highest mole fractions.