Alessandro Trovarelli

Prof. Alessandro Trovarelli

Dipartimento Politecnico, via del Cotonificio 108, Università di Udine, Udine, Italy
orcid

Research Focus & Metrics

Academic Career Length

39Years (1988-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 November 1996 in Catalysis Reviews
Verified
Journal Article
Closed access
Alessandro TrovarelliAlessandro Trovarelli
Alessandro Trovarelli
Over the past several years, cerium oxide and CeO2-containing materials have come under intense scrutiny as catalysts and as structural and electronic promoters of heterogeneous catalytic reactions. Recent developments regarding the characterization of ceria and CeO2-containing catalysts are critically reviewed with a special focus towards catalyst interaction with small molecules such as hydrogen, carbon monoxide, oxygen, and nitric oxide. Relevant catalytic and technological applications such as the use of ceria in automotive exhaust emission control and in the formulation of SO x reduction catalysts is described. A survey of the use of CeO2-containing materials as oxidation and reduction catalysts is also presented.

1 April 1999 in Catalysis Today
Verified
Journal Article
Closed access
Alessandro TrovarelliAlessandro Trovarelli
Alessandro Trovarelli
CLCarla de Leitenburg
Carla de Leitenburg
MBMarta Boaro
Marta Boaro
GDGiuliano Dolcetti
Giuliano Dolcetti

1 January 1995 in Journal of Catalysis
Verified
Journal Article
Closed access
Paolo FornasieroPaolo Fornasiero
Paolo Fornasiero
RDR. Dimonte
R. Dimonte
GRG.R. Rao
G.R. Rao
JKJan Kaspar
Jan Kaspar
SMS. Meriani
S. Meriani
MGM. Graziani
M. Graziani

16 June 2017 in ACS Catalysis
Verified
Journal Article
Open access
Alessandro TrovarelliAlessandro Trovarelli
Alessandro Trovarelli
Jordi LlorcaJordi Llorca
Jordi Llorca
Engineering the shape and size of catalyst particles and the interface between different components of heterogeneous catalysts at the nanometer level can radically alter their performances. This is particularly true with CeO2-based catalysts, where the precise control of surface atomic arrangements can modify the reactivity of Ce4+/Ce3+ ions, changing the oxygen release/uptake characteristics of ceria, which, in turn, strongly affects catalytic performance in several reactions like CO, soot, and VOC oxidation, WGS, hydrogenation, acid–base reactions, and so on. Despite the fact that many of these catalysts are polycrystalline with rather ill-defined morphologies, experimental and theoretical studies on well-defined nanocrystals have clearly established that the exposure of specific facets can increase/decrease surface oxygen reactivity and metal–support interaction (for supported metal nanoparticles), consequently affecting catalytic reactions. Here, we want to address the most recent developments in this area, showing that shape (and size) modification, surface/face reconstruction, and faceting of ceria at the nanoscale level can offer an important tool to govern activity and stability in several reactions and imagine how this could contribute to future developments.

1 April 2010 in Applied Catalysis A: General
Verified
Journal Article
Closed access
AKA. Kambolis
A. Kambolis
HMH. Matralis
H. Matralis
Alessandro TrovarelliAlessandro Trovarelli
Alessandro Trovarelli
CPCh. Papadopoulou
Ch. Papadopoulou

13 December 2013 in ACS Catalysis
Verified
Journal Article
Closed access
Eleonora AneggiEleonora Aneggi
Eleonora Aneggi
DWDawid Wiater
Dawid Wiater
CLCarla de Leitenburg
Carla de Leitenburg
Jordi LlorcaJordi Llorca
Jordi Llorca
Alessandro TrovarelliAlessandro Trovarelli
Alessandro Trovarelli