The hardened cement paste powder (HCP) powder, devoid of the hydration cementing property, can be regenerated and cemented into a test block with practical strength of almost 60 MPa via CO2 carbonization using appropriate means. This study established a kinetic model of CO2 curing of an HCP powder test block based on the degree of carbonization to study the carbonization reaction kinetic characteristics of the test block. The model was modified according to the characteristics of the evident temperature differences in the reaction kettle in the early, middle, and late stages of the carbonization process. The proposed model can be used to formulate and control the carbonization and cementation processes of HCP powder and can also be applied to describe the kinetics of the reaction processes of other similar systems.
Recycled concrete is a heterogeneous composite material, and the composition and volume fraction of each phase affect its macroscopic properties. In this paper, ANSYS APDL was used to construct a two-dimensional numerical model of recycled aggregate concrete with different replacement rates of recycled aggregate (0%, 25%, 50%, 75% and 100%), and a uniaxial compression test was carried out to explore the relationship between recycled aggregate content and its macroscopic mechanical behavior. On this basis, the numerical simulation of different strain rates (0.1 s−1, 0.05 s−1, 0.01 s−1, 0.005 s−1 and 0.001 s−1) was carried out. It was found that with the increase in the recycled aggregate replacement rate, the peak stress decreases first and then increases, and the peak strain increases continuously. When the replacement rate of recycled aggregate exceeds 50%, the overall damage area of the material increases rapidly. The strain rate will change the path of the micro-crack initiation and expansion of recycled concrete, as well as the process of damage accumulation and evolution. As a result, the unit area and shape of recycled concrete are different at different strain rates, and the damage degree of each phase material is also different.