Tea waste contains various substances with phenolic hydroxyl groups, including lignin, tannins, tea polyphenols, etc., which are rarely utilized. In this study, tea waste was directly dispersed with graphene oxide to prepare tea waste/reduced graphene oxide (TW/rGO) hydrogel through a one-step hydrothermal method. The prepared hydrogel presented a continuous three-dimensional porous structure and exhibited good mechanical properties with a compressive strength of 53.4 ± 4.0 kPa. It also showed excellent electrochemical performance as an electrode material. Its specific capacitance reached 434.7 F g⁻¹ at a current density of 1 A g⁻¹, and its capacitance retention was 55.8% when the current density was increased to 100 A g⁻¹. In addition, an TW/rGO assembled all-solid-state supercapacitor demonstrated a superior specific capacitance of 372.8 F g⁻¹ and a competitive energy density of 12.9 Wh kg⁻¹ at 1 A g⁻¹.